Achyrophanite

(K,Na)3(Fe3+,Ti,Al,Mg)5O2(AsO4)5
IMA status
  • Approved
IMA symbol
Aph
IMA approved
2018
Also known as
  • Achyrophaniet
  • IMA2018-011

Where it forms, where it's found

Geological setting

The temperature in this area was ca. 430 °C sublimates of the Arsenatnaya fumarole

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent
Colour
straw-yellow to golden yellow
Streak
white
Tenacity
brittle
Cleavage
Perfect

(001)

parallel intergrowths of flattened acicular crystals are flexible and elastic.

Fracture
Irregular/Uneven
Density
3.814 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 60 – 10°
Refractive index
1.823 – 1.895
Surface relief
Very high
Principal indices
nα 1.823 · nβ 1.840 · nγ 1.895
Pleochroism
Weak

Z (very pale yellow) > Y = X (colorless).

Dispersion
weak, r > v.
Extinction
Extinction is straight
Michel-Lévy diagramhighlighted lineδ = 0.0720
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]720 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation720 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
P2 2 21
Cell parameters
a = 6.5824(2) Å · b = 13.2488(4) Å · c = 10.7613(3) Å
Ratio a:b:c
1 : 2.013 : 1.635
Z
2
Twinning

Achyrophanite is microtwinned: twinning by merohedry Class I with the twin domains ratio 53/47 was found in the studied crystal.

Type-locality form

long-prismatic to acicular or, rarer, tabular crystals up to 0.02 × 0.2 × 1.5 mm, which form parallel, radiating, bush-like, or chaotic aggregates up to 3 mm across

Comment

new structure type

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic574.922374.610
22.20%
8OOxygenOxygen2215.999351.978
20.85%
26FeIronIron555.845279.225
16.54%
22TiTitaniumTitanium547.867239.335
14.18%
13AlAluminiumAluminium526.982134.910
7.99%
12MgMagnesiumMagnesium524.305121.525
7.20%
19KPotassiumPotassium339.098117.294
6.95%
11NaSodiumSodium322.99068.970
4.09%
Total1687.847100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Achyrophaniet
  • IMA2018-011

In other languages

German
Achyrophanit · IMA 2018-011

Classification

Strunz
10th ed.

8.BF.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BFWith medium-sized and large cations, (OH, etc.):RO4< 0.5:1Group
  • 8.BF.30AchyrophaniteSpecies

Literature, links & citation

Citations
  1. 2018Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2018) CNMNC Newsletter No 43, New minerals and nomenclature modifications approved in 2018. Mineralogical Magazine, 82 (3) 779-785 doi:10.1180/mgm.2018.72DOI: 10.1180/mgm.2018.72
  2. 2022(2022) Achyrophanite. Handbook of Mineralogy. Mineralogical Society of America
  3. 2025Pekov, Igor V.; Zubkova, Natalia V.; Koshlyakova, Natalia N.; Belakovskiy, Dmitry I.; Vigasina, Marina F.; Agakhanov, Atali A.; Britvin, Sergey N.; Turchkova, Anna G.; Sidorov, Evgeny G.; Zhegunov, Pavel S.; et al. (2025) Achyrophanite, (K,Na)3(Fe3+,Ti,Al,Mg)5O2(AsO4)5, a New Mineral with the Novel Structure Type from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Minerals, 15 (7). doi:10.3390/min15070706DOI: 10.3390/min15070706
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Achyrophanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/achyrophanite-52919},
  note      = {Accessed 2026-05-11}
}