Afwillite

Ca3[SiO4][SiO2(OH)2] · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Afw
Discovered
1925
Also known as
  • Afwillitt

Where it forms, where it's found

Geological setting

In a large dolerite inclusion in kimberlite.

Contact metamorphism of limestones.

Type locality
Dutoitspan Mine
  1. KEM JV Mine (Kimberley Ekapa Mining Joint Venture mine
  2. Kimberley Underground mine)
  3. Kimberley
  4. Sol Plaatje Local Municipality
  5. Frances Baard District Municipality
  6. Northern Cape
  7. South Africa

-28.7607°, 24.7994°

45recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Colourless · white · rarely blue
Streak
White
Tenacity
brittle
Cleavage
Perfect

Perfect on (101), good on (100)

Fracture
Conchoidal
Density
2.630 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 50 – 56°
Refractive index
1.6169 – 1.6336
Surface relief
Moderate
Principal indices
nα 1.6169 · nβ 1.6204 · nγ 1.6336
Dispersion
r < v
Extinction
Y = b; X ∧ c = 31.2°.
Michel-Lévy diagramhighlighted lineδ = 0.0167
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]167 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation167 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#3
Cell parameters
a = 16.278(1) Å · b = 5.6321(4) Å · c = 13.236(1) Å
Cell angles
β = 134.9 °
Ratio a:b:c
1 : 0.346 : 0.813
Z
4
Morphology

Crystals are prismatic, tabular, radial fibrous spherulites, massive. Known forms include (001), (100), (110), (310), (011), (045), (013), (101), (101), (302), (112), (121), (211), (213), (312).

Type-locality form

Large crystals (11 x 4 x 1.5 cm) composed of sub-parallel individuals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
46.72%
20CaCalciumCalcium340.078120.234
35.11%
14SiSiliconSilicon228.08556.170
16.40%
1HHydrogenHydrogen61.0086.048
1.77%
Total342.442100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Fe
  • Mg
  • F

Synonyms

  • Afwillitt

In other languages

French
Afwillite
German
Afwillit
Spanish
Afwillita
Italian
afwillite
Chinese
柱硅钙石
Russian
Афвиллит
Arabic
أفويليت

Classification

Strunz
10th ed.

9.AG.75

  • 9SilicatesClass
  • 9.ANesosilicatesDivision
  • 9.AGNesosilicates with additional anions; cations in > [6] +- [6] coordinationGroup
  • 9.AG.75AfwilliteSpecies
Dana
8th ed.

52.04.07.01

  • 52Nesosilicates Insular Sio4 Groups and O, Oh, F, H2oClass
  • 52.04Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] and/or >[6] coordinationType
  • 52.04.07Afwillite and related speciesGroup
  • 52.04.07.01AfwilliteSpecies
CIM

14.5.11

  • 14Silicates not Containing AluminumClass
  • 14.5Silicates of CaGroup
  • 14.5.11AfwilliteSpecies

Literature, links & citation

Citations
  1. 1925Foshag, W.F. (1925) New minerals: new species. American Mineralogist: 10: 447-448.
  2. 1925Parry, John, Wright, F. E. (1925) Afwillite, a new hydrous calcium silicate, from Dutoitspan mine, Kimberley, South Africa. Mineralogical Magazine and Journal of the Mineralogical Society, 20 (108) 277-286 doi:10.1180/minmag.1925.020.108.02 DOI: 10.1180/minmag.1925.020.108.02
  3. 1930Tilley, C. E. (1930) An Association of Afwillite with Spurrite. Geological Magazine, 67 (4) 168-169 doi:10.1017/s0016756800099143DOI: 10.1017/s0016756800099143
  4. 1949Megaw, H. D. (1949) Hydroxyl groups in afwillite. Acta Crystallographica, 2 (6) 419-420 doi:10.1107/s0365110x49001089DOI: 10.1107/s0365110x49001089
  5. 1952Moody, K. M. (1952) The thermal decomposition of afwillite. Mineralogical Magazine and Journal of the Mineralogical Society, 29 (216) 838-840 doi:10.1180/minmag.1952.029.216.05 DOI: 10.1180/minmag.1952.029.216.05
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Afwillite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/afwillite-42},
  note      = {Accessed 2026-05-11}
}