Agrinierite

K2Ca[(UO2)3O3(OH)2]2 · 5H2O
IMA status
  • Approved
IMA symbol
Agn
IMA approved
1971
Also known as
  • Agrinieriet
  • Agrinieritt
  • IMA1971-046

Where it forms, where it's found

Geological setting

oxidation zone of a uranium deposit

Type locality
Margnac Mine
  1. Compreignac
  2. Bellac
  3. Haute-Vienne
  4. Nouvelle-Aquitaine
  5. France

45.9973°, 1.3136°

2recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Transparency
Transparent · Translucent
Colour
Orange
Cleavage
Distinct/Good

on (001)

Density
5.7 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 55°
Refractive index
2.01 – 2.06
Surface relief
Very high
Principal indices
nβ 2.01 · nγ 2.06
Dispersion
relatively weak

Crystallography

Crystal system
Monoclinic
Space group
Cm
Cell parameters
a = 14.069(3) Å · b = 14.220(3) Å · c = 13.967(3) Å
Cell angles
β = 120.24(12) °
Ratio a:b:c
1 : 1.011 : 0.993
Unit cell volume
2412.2 ų
Z
2
Morphology

Crystals tabular on (001), pseudohexagonal in section

Twinning

Sector twins with composition plane (110)

Comment

pseudo-orthorhombic due to structure twinning by metric merohedry (diffraction type I; Plášil et al. 2021), i.e., due to a mirror in (101); (F-centred) supercell data: a = 14.121 Å, b = 14.276 Å, c = 24.221 Å, V = 2 × 2441 Å ³

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
92UUraniumUranium6238.0291428.174
71.68%
8OOxygenOxygen2715.999431.973
21.68%
19KPotassiumPotassium239.09878.196
3.92%
20CaCalciumCalcium140.07840.078
2.01%
1HHydrogenHydrogen141.00814.112
0.71%
Total1992.533100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Agrinieriet
  • Agrinieritt
  • IMA1971-046

In other languages

French
agriniérite
German
Agrinierit · IMA 1971-046
Italian
agrinierite
Chinese
钾钙锶铀矿
Russian
Агриньерит

Classification

Strunz
10th ed.

4.GB.05

  • 4OxidesClass
  • 4.GUranyl HydroxidesDivision
  • 4.GBWith additional cations (K, Ca, Ba, Pb, etc.); with mainly UO2(O,OH)5 pentagonal polyhedraGroup
  • 4.GB.05AgrinieriteSpecies
Dana
8th ed.

05.05.01.01

  • 05Oxides Containing Uranium or ThoriumClass
  • 05.05AX3O10·xH2OType
  • 05.05.01— unnamed intermediate level —Group
  • 05.05.01.01AgrinieriteSpecies
CIM

7.16.13

  • 7Oxides and HydroxidesClass
  • 7.16Oxides of UGroup
  • 7.16.13AgrinieriteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1972Cesbron, F., Brown, W. L., Bariand, P., Geffroy, J. (1972) Rameauite and agrinierite, two new hydrated complex uranyl oxides from Margnac, France. Mineralogical Magazine, 38 (299) 781-789 doi:10.1180/minmag.1972.038.299.01 DOI: 10.1180/minmag.1972.038.299.01
  2. 1973Fleischer, M. (1973) New mineral names. American Mineralogist, 58 (7-8). 805-807
  3. 1997Anthony, John Williams, Bideaux, Richard A., Bladh, Kenneth W., Nichols, Monte C. - Ed. (1997) Handbook of Mineralogy Vol. 3 - Halides, Hydroxides, Oxides. Mineral Data Publishing, Tucson, Arizona. p.1-682.
  4. 2000Cahill, C. L., Burns, P. C. (2000) The structure of agrinierite: a Sr-containing uranyl oxide hydrate mineral. American Mineralogist, 85 (9) 1294-1297 doi:10.2138/am-2000-8-922 DOI: 10.2138/am-2000-8-922
  5. 2005(2005) Agrinierite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Agrinierite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/agrinierite-58},
  note      = {Accessed 2026-05-11}
}