Ahlfeldite

Ni(SeO3) · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Afe
Discovered
1935

Where it forms, where it's found

Geological setting

alteration product of nickel-bearing selenides and sulfides.

Alteration product of nickel sulfides and selenides

Type locality
Virgen de Surumi mine
  1. Pakajake Canyon
  2. Colquechaca Municipality
  3. Chayanta Province
  4. Potosí
  5. Bolivia

-18.6500°, -66.0167°

2recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
apple-green · brown · pink · yellowish

Becomes more pink with increasing cobalt content.

Streak
pale green, white
Tenacity
brittle
Cleavage
Imperfect/Fair

Fair on (110)(103)

Density
3.37 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 85° · 2V calc = 82°
Refractive index
1.709 – 1.787
Surface relief
High
Principal indices
nα 1.709 · nβ 1.752 · nγ 1.787
Pleochroism
Visible

X = pale green; Y = pale pink; Z = pink.

Dispersion
r < v strong
Extinction
Y = b; Z ∧ c = –16°.
Michel-Lévy diagramhighlighted lineδ = 0.0780
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]780 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation780 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 7.53 Å · b = 8.76 Å · c = 6.43 Å
Cell angles
β = 99.08 °
Ratio a:b:c
1 : 1.163 : 0.854
Z
4
Morphology

Rare crystals to 1mm, crusts, spherical aggregates

Type-locality form

Rare crystals, to 1 mm; in crystalline crusts and spherical aggregates.

Comment

Space Group: P21/n.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen515.99979.995
36.08%
34SeSeleniumSelenium178.97178.971
35.62%
28NiNickelNickel158.69358.693
26.48%
1HHydrogenHydrogen41.0084.032
1.82%
Total221.691100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Co

In other languages

French
ahlfeldite
German
Ahlfeldit · Nickelseleniat
Spanish
Ahlfeldita
Italian
ahlfeldite
Chinese
水硒镍石
Russian
Альфильдит
Arabic
آلفيلديت

Classification

Strunz
10th ed.

4.JH.10

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JHSelenites without additional anions, with H2OGroup
  • 4.JH.10AhlfelditeSpecies
Dana
8th ed.

34.02.03.03

  • 34Selenites, Tellurites and SulfitesClass
  • 34.02A(XO3)·xH2OType
  • 34.02.03Chalcomenite Group (Monoclinic)Group
  • 34.02.03.03AhlfelditeSpecies
CIM

28.1.13

  • 28Selenites, Selenates, Tellurites, and TelluratesClass
  • 28.1SelenitesGroup
  • 28.1.13AhlfelditeSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Boletín Facultad de cienncias exactus, físicas y naturals, Universidad nacional de Córdoba: 7: 1-4.
  2. 1935Herzenberg, R., Ahlfeld, F. (1935) Blockit, ein neues Selenerz aus Bolivien. Zentralblatt Mineralien, Abteilung A: 6: 277-279.
  3. 1945Herzenberg, R. (1945) Inst. Boliviano de Ing. De Minas y Geol., Publ. Técu, La Paz, no. 5.
  4. 1945Herzenberg, R. (1945) Mineria Boliviana: 2: no. 25.
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ahlfeldite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ahlfeldite-61},
  note      = {Accessed 2026-05-11}
}