Alum-(Na)

NaAl(SO4)2 · 12H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Aum-Na
Also known as
  • Na Alum
  • Sodalumit
  • Sodalumita
  • +3 more

Where it forms, where it's found

14recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless
Density
1.64 g/cm³

Optical

Optical type
Isotropic
Surface relief
Low
Principal indices
n 1.4388
Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.439

Crystallography

Crystal system
Isometric
Space group
Pa3
Cell parameters
a = 12.214(1) Å
Z
4
Comment

Synthetic material

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2015.999319.980
69.82%
16SSulfurSulfur232.06064.120
13.99%
13AlAluminiumAluminium126.98226.982
5.89%
1HHydrogenHydrogen241.00824.192
5.28%
11NaSodiumSodium122.99022.990
5.02%
Total458.264100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Na Alum
  • Sodalumit
  • Sodalumita
  • Sodalumite
  • Sodium Alum
  • γ alum

In other languages

German
Alaun-(Na)
Italian
Alum- · alum-(Na) · Sodio-allume

Classification

Strunz
10th ed.

7.CC.20

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CCWith medium-sized and large cationsGroup
  • 7.CC.20Alum-(Na)Species
Dana
8th ed.

29.05.05.02

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.05AB(XO4)2·xH2OType
  • 29.05.05Alum GroupGroup
  • 29.05.05.02Alum-(Na)Species
CIM

25.6.14

  • 25SulphatesClass
  • 25.6Sulphates of Al and TlGroup
  • 25.6.14Alum-(Na)Species

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  2. 1967Cromer, D. T., Kay, M. I., Larson, A. C. (1967) Refinement of the alum structures. II. X-ray and neutron diffraction of NaAl(SO4)2.12H2O, γ alum. Acta Crystallographica, 22 (2) 182-187 doi:10.1107/s0365110x67000313DOI: 10.1107/s0365110x67000313
  3. 2005(2005) Alum-(Na). Handbook of Mineralogy. Mineralogical Society of America
  4. 2008Burke, Ernst A. J. (2008) Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks. The Mineralogical Record, 39 (2) 131-135
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Alum-(Na) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/alum-na-3703},
  note      = {Accessed 2026-05-11}
}