Ambrinoite

[K,(NH4)]2(As,Sb)6(Sb,As)2S13 · H2O
IMA status
  • Approved
IMA symbol
Amb
Discovered
1998
IMA approved
2009
Also known as
  • Ambrinoiet
  • Ambrinoitt
  • IMA2009-071

Where it forms, where it's found

Geological setting

Evaporite deposit.

Type locality
Signols Quarries
  1. Signols
  2. Oulx
  3. Metropolitan City of Turin
  4. Piedmont
  5. Italy

45.0529°, 6.8054°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent
Colour
Cinnabar-red
Streak
Red
Tenacity
brittle
Cleavage
Perfect

Perfect on (001) and (010); poor on (100).

Fracture
Splintery
Density
3.305 g/cm³

Optical

Pleochroism
Strong

Yellow along [100] and orange-red in a normal direction.

Notes

The mean refractive index should be 2.5(3), but could not be measured.

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 9.704(1) Å · b = 11.579(1) Å · c = 12.102(1) Å
Cell angles
α = 112.82(1) ° · β = 103.44(1) ° · γ = 90.40(1) °
Ratio a:b:c
1 : 1.193 : 1.247
Unit cell volume
1211.6 ų
Z
2
Morphology

Masses and groups of lamellae, elongated on [100] and flattened on (001).

Parting
Not observed
Type-locality form

Aggregates of tabular crystals up to 1 mm in length.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
51SbAntimonyAntimony8121.760974.080
45.89%
33AsArsenicArsenic874.922599.376
28.24%
16SSulfurSulfur1332.060416.780
19.64%
19KPotassiumPotassium239.09878.196
3.68%
7NNitrogenNitrogen214.00728.014
1.32%
8OOxygenOxygen115.99915.999
0.75%
1HHydrogenHydrogen101.00810.080
0.48%
Total2122.525100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ambrinoiet
  • Ambrinoitt
  • IMA2009-071

In other languages

German
Ambrinoit · IMA 2009-071
Italian
ambrinoite

Classification

Strunz
10th ed.

2.HE.10

  • 2Sulfides and SulfosaltsClass
  • 2.HSulfosalts of SnS archetypeDivision
  • 2.HEWith alkalies, H2OGroup
  • 2.HE.10AmbrinoiteSpecies
Dana
8th ed.

03.08.08.02

  • 03SulfosaltsClass
  • 03.081 < ø < 2Type
  • 03.08.08— unnamed intermediate level —Group
  • 03.08.08.02AmbrinoiteSpecies

Literature, links & citation

Citations
  1. 2010Bonaccorsi, E. et al. (2010): Ambrinoite (K,NH4)2(As,Sb)8S13·H2O, the first natural (K,NH4)-hydrated sulfosalt, from Signols (Piedmont, Italy). 22th General Meeting of the IMA (IMA2010), Budapest, Hungary, August 21-27, CD of Abstracts, p. 494.
  2. 2011Biagioni, C., Bonaccorsi, E., Pasero, M., Moëlo, Y., Ciriotti, M. E., Bersani, D., Callegari, A. M., Boiocchi, M. (2011) Ambrinoite, (K,NH4)2(As,Sb)8S13·H2O, a new mineral from Upper Susa Valley, Piedmont, Italy: The first natural (K,NH4)-hydrated sulfosalt. American Mineralogist, 96 (5). 878-887 doi:10.2138/am.2011.3723 DOI: 10.2138/am.2011.3723
  3. 2021(2021) Ambrinoite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ambrinoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ambrinoite-39789},
  note      = {Accessed 2026-05-11}
}