Ammineite

CuCl2 · 2NH3
IMA status
  • Approved
IMA symbol
Amm
IMA approved
2008
Also known as
  • Ammineiet
  • Ammineitt
  • IMA2008-032

Where it forms, where it's found

Geological setting

Interaction between NH3 from bird guano and Cu from plutonic rocks in a dry environment.

Type locality
Pabellón de Pica
  1. Chanabaya
  2. Iquique
  3. Iquique Province
  4. Tarapacá
  5. Chile

-20.9089°, -70.1381°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Deep blue to sky blue
Streak
Light blue
Cleavage
Perfect

(001) perfect, (110) good

Tenacity described as 'weak' in type description

Density
2.34 g/cm³

Optical

Optical type
Biaxial (+) · 2V calc = 76°
Refractive index
1.676 – 1.785
Surface relief
High
Principal indices
nα 1.676 · nβ 1.715 · nγ 1.785
Pleochroism

β and γ = dark blue, α = light blue

Dispersion
Could not be observed because of the intense blue color
UV response
Not fluorescent
Notes

X = c, Y = b and Z = a

Michel-Lévy diagramhighlighted lineδ = 0.1090
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1090 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1090 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#50
Cell parameters
a = 7.688 Å · b = 10.645 Å · c = 5.736 Å
Ratio a:b:c
1 : 1.385 : 0.746
Morphology

Elongate along [100], with the dominant form (001)

Type-locality form

Intense sky-blue hypidiomorphic grains up to 3 millimeters across. Also as powdery masses in solution cavities of halite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine235.45070.900
42.08%
29CuCopperCopper163.54663.546
37.71%
7NNitrogenNitrogen214.00728.014
16.62%
1HHydrogenHydrogen61.0086.048
3.59%
Total168.508100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ammineiet
  • Ammineitt
  • IMA2008-032

In other languages

German
Ammineit · IMA 2008-032
Italian
ammineite

Classification

Strunz
10th ed.

3.C0

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.C0— unnamed intermediate level —Group
  • 3.C0AmmineiteSpecies

Literature, links & citation

Citations
  1. 2010Echigo, T., Kimata, M. (2010) Crystal Chemistry and Genesis of Organic Minerals: a Review of Oxalate and Polycyclic Aromatic Hydrocarbon Minerals. The Canadian Mineralogist, 48 (6) 1329-1357 doi:10.3749/canmin.48.5.1329DOI: 10.3749/canmin.48.5.1329
  2. 2010Bojar, H.-P., Walter, F., Baumgartner, J., Farber, G. (2010) Ammineite, CuCl2(NH3)2, a new species containing an ammine complex: mineral data and crystal structure. The Canadian Mineralogist, 48 (6) 1359-1371 doi:10.3749/canmin.48.5.1359 DOI: 10.3749/canmin.48.5.1359
  3. 2011Russo, M., Campostrini, I. (2011) Ammineite, matlockite and post 1944 eruption fumarolic minerals at Vesuvius. Plinius: 37: 312-312.
  4. 2017(2017) Ammineite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2023Košek, Filip, Němec, Ivan, Jehlička, Jan (2023) Raman study of several Cu‐bearing complex minerals from the guano deposit at Pabellón de Pica, Tarapaca region, Chile. Journal of Raman Spectroscopy, 54 (11) 1172-1182 doi:10.1002/jrs.6506DOI: 10.1002/jrs.6506
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ammineite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ammineite-38895},
  note      = {Accessed 2026-05-11}
}