Annivite-(Zn)

Cu6(Cu4Zn2)Bi4S12S
IMA status
  • Approved
IMA symbol
Anv-Zn
Also known as
  • Anniviet-(Zn)
  • Annivitt-(Zn)
  • IMA2023-124

Where it forms, where it's found

Geological setting

five element ore deposit

Type locality
Geister vein
  1. Rovnost Mine
  2. Jáchymov
  3. Karlovy Vary District
  4. Karlovy Vary Region
  5. Czech Republic

50.3690°, 12.8971°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
dark grey
Streak
grey
Tenacity
brittle
Cleavage
Poor/Indistinct
Fracture
Conchoidal
Density
5.259 g/cm³

Optical

Optical colour
pale grey, with brownish shade
Internal reflections
very rare in pale brown tints
Tropism
Isotropic
Reflectance R%
(32.3) 470, (32.0) 546, (32.0) 589, (31.6) 640
Reflected-light panel
32.0 %isotropic · single curve
Specimen sRGB 203, 142, 78
White reference100 % reflector under same lamp
Reflected colour
pale grey, with brownish shade
Internal reflections
very rare in pale brown tints

Crystallography

Crystal system
Isometric
Space group
#210
Cell parameters
a = 10.3545(6) Å
Z
2
Type-locality form

anhedral grains, up to 50 μm in size, and growth zones (up to 100 μm in thickness) in zoned annivite(Zn)/tennantite-(Zn) grains

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth4208.980835.920
41.40%
29CuCopperCopper1063.546635.460
31.48%
16SSulfurSulfur1332.060416.780
20.64%
30ZnZincZinc265.380130.760
6.48%
Total2018.920100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Anniviet-(Zn)
  • Annivitt-(Zn)
  • IMA2023-124

In other languages

German
Annivit-(Zn)
Italian
Annivite- · annivite-(Zn)

Classification

Strunz
10th ed.

2.GB

  • 2Sulfides and SulfosaltsClass
  • 2.GSulfarsenites, sulfantimonites, sulfbismuthitesDivision
  • 2.GBNeso-sulfarsenites, etc. with additional SGroup
  • 2.GBAnnivite-(Zn)Species

Literature, links & citation

Citations
  1. Sejkora, J., Biagioni, C., Dolníček, Z., Velebil, D. and Škácha, P. (2024) Annivite- (Zn), IMA 2023-124. CNMNC Newsletter 79, Mineralogical Magazine, 88
  2. 2003Klünder, Maiken Hansen, Karup-Møller, Sven, Makovicky, Emil (2003) Exploratory studies on substitutions in the tetrahedrite-tennantite solid solution series Part III. The solubility of bismuth in tetrahedrite-tennantite containing iron and zinc. Neues Jahrbuch für Mineralogie - Monatshefte, 2003 (4) 153-175 doi:10.1127/0028-3649/2003/2003-0153DOI: 10.1127/0028-3649/2003/2003-0153
  3. 2025Sejkora, Jiří; Biagioni, Cristian; Dolníček, Zdeněk; Velebil, Dalibor; Škácha, Pavel (2025) Annivite-(Zn), Cu6(Cu4Zn2)Σ6Bi4S13, from the Jáchymov ore district, Czech Republic: the first Bi-dominant member of the tetrahedrite group. Mineralogical Magazine, 89 (1). 102-112 doi:10.1180/mgm.2024.54DOI: 10.1180/mgm.2024.54
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Annivite-(Zn) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/annivite-zn-471103},
  note      = {Accessed 2026-05-11}
}