Aravaipaite

Pb3AlF9 · H2O
IMA status
  • Approved
IMA symbol
Avp
Discovered
1988
IMA approved
1988
Also known as
  • Aravaipaiet
  • Aravaipaitt
  • IMA1988-021

Where it forms, where it's found

Geological setting

oxidized zone of an epithermal Pb-Cu-Ag deposit hosted by a silicified rhyolite-schist breccia

Type locality
Grand Reef Mine
  1. Laurel Canyon
  2. Grand Reef Mountain
  3. Klondyke
  4. Aravaipa Mining District
  5. Graham County
  6. Arizona
  7. USA

32.8825°, -110.3175°

2recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless
Streak
White
Tenacity
elastic
Cleavage
Perfect

micaceous on (010); good on (100), (001), (101), (101)

Fracture
Irregular/Uneven
Density
6.37 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 70 – 73° · 2V calc = 66°
Refractive index
1.678 – 1.694
Surface relief
High
Principal indices
nα 1.678 · nβ 1.69 · nγ 1.694
Dispersion
r < v, strong
Michel-Lévy diagramhighlighted lineδ = 0.0160
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]160 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation160 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.842 Å · b = 25.2 Å · c = 5.652 Å
Cell angles
α = 93.84 ° · β = 90.14 ° · γ = 85.28 °
Ratio a:b:c
1 : 4.314 : 0.967
Z
4
Morphology

Platy crystals, flattened on (010).

Twinning

polysynthetic on (010), universal

Type-locality form

platy crystals to 3 mm

Comment

Originally thought to be monoclinic, P21/n, with a = 25.048(4), b = 5.8459(8), c = 5.6505(7) Å, β = 94.013(3)°. Kampf et al. (2011): "Twinning may be responsible for the original monoclinic cell or the two structures could be order-disorder (OD) polytypes."

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead3207.200621.600
74.22%
9FFluorineFluorine918.998170.982
20.41%
13AlAluminiumAluminium126.98226.982
3.22%
8OOxygenOxygen115.99915.999
1.91%
1HHydrogenHydrogen21.0082.016
0.24%
Total837.579100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Aravaipaiet
  • Aravaipaitt
  • IMA1988-021

In other languages

German
Aravaipait · IMA 1988-021
Italian
aravaipaite

Classification

Strunz
10th ed.

3.BB.35

  • 3HalidesClass
  • 3.BSimple halides, with H2ODivision
  • 3.BBM:X = 1:2Group
  • 3.BB.35AravaipaiteSpecies
Dana
8th ed.

11.06.19.01

  • 11Halide ComplexesClass
  • 11.06Aluminofluorides - Isolated OctahedraType
  • 11.06.19— unnamed intermediate level —Group
  • 11.06.19.01AravaipaiteSpecies
CIM

8.8.19

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.8Halides of PbGroup
  • 8.8.19AravaipaiteSpecies

Literature, links & citation

Citations
  1. 1989Kampf, Anthony R., Dunn, Pete J., Foord, Eugene E. (1989) Grandreefite, pseudograndreefite, laurelite, and aravaipaite: Four new minerals from the Grand Reef mine, Graham County, Arizona. American Mineralogist, 74 (7-8) 927-933
  2. 1996Foord, Eugene E., Kampf, Anthony R. (1996) Calcioaravaipaite, a New Mineral, and Associated Lead Fluoride Minerals from the Grand Reef Mine, Graham County, Arizona. The Mineralogical Record, 27 (4) 293-300
  3. 1997Anthony, J.W. et al. (1997) Handbook of Mineralogy, Vol. 3, 20.
  4. 2001Kampf, Anthony R. (2001) The crystal structure of aravaipaite. American Mineralogist, 86 (7) 927-931 doi:10.2138/am-2001-0717 DOI: 10.2138/am-2001-0717
  5. 2005(2005) Aravaipaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Aravaipaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/aravaipaite-311},
  note      = {Accessed 2026-05-11}
}