Argesite

(NH4)7Bi3Cl16
IMA status
  • Approved
IMA symbol
Age
IMA approved
2011
Also known as
  • Argesiet
  • Argesitt
  • IMA2011-072

Where it forms, where it's found

Geological setting

In an active medium-temperature (~250 °C) intracrater fumarole on a pyroclastic breccia.

Type locality
La Fossa crater
  1. Vulcano Island
  2. Lipari
  3. Eolie Islands (Aeolian Islands)
  4. Metropolitan City of Messina
  5. Sicily
  6. Italy

38.4034°, 14.9614°

1recorded occurrences
Source · OpenStreetMap

Physical

Colour
Pale yellow
Streak
White
Cleavage
None Observed
Fracture
Conchoidal
Density
2.88 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.725 – 1.731
Surface relief
High
Principal indices
nω 1.731 · nε 1.725
UV response
Non-fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0060
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]60 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation60 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
R-3c
Cell parameters
a = 13.093(1) Å · c = 102.682(9) Å
Unit cell volume
15245 ų
Z
18
Morphology

Habit is almost tabular [according to the (001) pinacoid] and in most cases is very complex, due to the presence of various rhombohedra and bipyramids.

Type-locality form

Pale-yellow crystals up to 0.15 mm in length.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth3208.980626.940
47.48%
17ClChlorineChlorine1635.450567.200
42.96%
7NNitrogenNitrogen714.00798.049
7.42%
1HHydrogenHydrogen281.00828.224
2.14%
Total1320.413100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Argesiet
  • Argesitt
  • IMA2011-072

In other languages

German
Argesit · IMA 2011-072
Italian
argesite

Classification

Strunz
10th ed.

7.CD

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CDWith only large cationsGroup
  • 7.CDArgesiteSpecies

Literature, links & citation

Citations
  1. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2011. CNMNC Newsletter No 11. Mineralogical Magazine, 75 (6) 2887-2893 doi:10.1180/minmag.2011.075.6.2887 DOI: 10.1180/minmag.2011.075.6.2887
  2. 2012Demartin, F., Campostrini, I., Castellano, C., Gramaccioli, C. M. (2012) Argesite, (NH4)7Bi3Cl16, a new mineral from La Fossa Crater, Vulcano, Aeolian Islands, Italy: A first example of the [Bi2Cl10]4- anion. American Mineralogist, 97 (8) 1446-1451 doi:10.2138/am.2012.4052 DOI: 10.2138/am.2012.4052
  3. 2017(2017) Argesite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Argesite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/argesite-42369},
  note      = {Accessed 2026-05-11}
}