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","Arrojadite Group. Arrojadite-(KFe)-Dickinsonite-(KMnNa) Series.","Originally named arrojadite for Miguel Arrojado Lisbôa, Brazilian geologist; redefinition after the new arrojadite nomenclature (CNMMN 05-D, October 2005).","2025-08-11 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u003C\u002Fsub>(PO\u003Csub>3\u003C\u002Fsub>OH)F\u003Csub>2\u003C\u002Fsub>","(Ba◻)(NaNa)Ca(Na\u003Csub>2\u003C\u002Fsub>◻)Mg\u003Csub>13\u003C\u002Fsub>Al(PO\u003Csub>4\u003C\u002Fsub>)\u003Csub>11\u003C\u002Fsub>(PO\u003Csub>3\u003C\u002Fsub>OH)F\u003Csub>2\u003C\u002Fsub>",{"id":138,"name":139,"entrytype":9,"csystem":40,"ima_formula":140,"mindat_formula":141,"hmin":130,"hmax":11,"dmeas":11,"dcalc":142,"primary_image_id":11},54651,"Manganoarrojadite-(KNa)","KNa\u003Csub>5\u003C\u002Fsub>MnFe\u003Csub>13\u003C\u002Fsub>Al(PO\u003Csub>4\u003C\u002Fsub>)\u003Csub>11\u003C\u002Fsub>(PO\u003Csub>3\u003C\u002Fsub>OH)(OH)\u003Csub>2\u003C\u002Fsub>","(KNa)(NaNa)Mn\u003Csup>2+\u003C\u002Fsup>(Na\u003Csub>2\u003C\u002Fsub>◻)Fe\u003Csup>2+\u003C\u002Fsup>\u003Csub>13\u003C\u002Fsub>Al(PO\u003Csub>4\u003C\u002Fsub>)\u003Csub>11\u003C\u002Fsub>(PO\u003Csub>3\u003C\u002Fsub>OH)(OH)\u003Csub>2\u003C\u002Fsub>","3.53",{"id":144,"name":145,"entrytype":9,"csystem":40,"ima_formula":146,"mindat_formula":147,"hmin":11,"hmax":11,"dmeas":11,"dcalc":148,"primary_image_id":149},7294,"Sigismundite","BaFe\u003Csup>2+\u003C\u002Fsup>(CaNa\u003Csub>2\u003C\u002Fsub>)Fe\u003Csup>2+\u003C\u002Fsup>\u003Csub>13\u003C\u002Fsub>Al(PO\u003Csub>4\u003C\u002Fsub>)\u003Csub>11\u003C\u002Fsub>(PO\u003Csub>3\u003C\u002Fsub>OH)(OH)\u003Csub>2\u003C\u002Fsub>","(Ba◻)(Fe\u003Csup>2+\u003C\u002Fsup>◻)Ca(Na\u003Csub>2\u003C\u002Fsub>◻)Fe\u003Csup>2+\u003C\u002Fsup>\u003Csub>13\u003C\u002Fsub>Al(PO\u003Csub>4\u003C\u002Fsub>)\u003Csub>11\u003C\u002Fsub>(PO\u003Csub>3\u003C\u002Fsub>OH)(OH)\u003Csub>2\u003C\u002Fsub>","3.544",1949,[151],{"id":152,"name":153,"entrytype":9,"csystem":40,"ima_formula":154,"mindat_formula":155,"hmin":156,"hmax":157,"dmeas":158,"dcalc":46,"primary_image_id":159},142,"Alluaudite","◻NaMnFe\u003Csup>3+\u003C\u002Fsup>\u003Csub>2\u003C\u002Fsub>(PO\u003Csub>4\u003C\u002Fsub>)\u003Csub>3\u003C\u002Fsub>","(Na,Ca)Mn\u003Csup>2+\u003C\u002Fsup>(Fe\u003Csup>3+\u003C\u002Fsup>,Mn\u003Csup>2+\u003C\u002Fsup>,Fe\u003Csup>2+\u003C\u002Fsup>,Mg)\u003Csub>2\u003C\u002Fsub>(PO\u003Csub>4\u003C\u002Fsub>)\u003Csub>3\u003C\u002Fsub>",5.5,6,"3.4",843,[],[162,168],{"id":163,"txt":164,"latitude":165,"longitude":166,"country":167},444,"Serra Branca pegmatite, Pedra Lavrada, Paraíba, Brazil",-6.833223,-36.518006,"Brazil",{"id":169,"txt":170,"latitude":171,"longitude":172,"country":173},4118,"Nickel Plate Mine, Keystone, Keystone Mining District, Pennington County, South Dakota, USA",43.8836111,-103.4125,"USA",46,[176,181,185,189,193,197,202,206,210,214,219,223,228],{"id":177,"year":178,"html":179,"doi":180},438267,1942,"Mason, Brian (1942) Some iron-manganese phosphate minerals from the pegmatite at Hühnerkobel in Bavaria. \u003Ci>Geologiska Föreningen i Stockholm Förhandlingar\u003C\u002Fi>,  64 (3) 335-340 \u003Ca target='_blank' href='https:\u002F\u002Fdoi.org\u002F10.1080\u002F11035894209446083'>doi:10.1080\u002F11035894209446083\u003C\u002Fa>","10.1080\u002F11035894209446083",{"id":182,"year":178,"html":183,"doi":184},17882288,"Guimarães, Djalma (1942) Arrojadite, a new mineral of the wagnerite group. \u003Ci>Boletim da Faculdade de Filosofia, Ciências e Letras da Universidade de São Paulo. Mineralogia 5\u003C\u002Fi>, 3-16 \u003Ca target='_blank' href='https:\u002F\u002Fdoi.org\u002F10.11606\u002Fbmffclusp.v0i5.121334'>doi:10.11606\u002Fbmffclusp.v0i5.121334\u003C\u002Fa>","10.11606\u002Fbmffclusp.v0i5.121334",{"id":186,"year":187,"html":188,"doi":11},16101405,1946,"Eriksson (1946) Arkiv för Kemi, Mineralogi och Geologi, Stockholm: 23A, no. 8. [as Hühnerkobelite]",{"id":190,"year":191,"html":192,"doi":11},521954,1950,"Lindberg, Marie Louise (1950) Arrojadite, hühnerkobelite, and graftonite. \u003Ci>American Mineralogist\u003C\u002Fi>,  35 (1-2) 59-76 \u003Ca target='_blank' href='http:\u002F\u002Fwww.minsocam.org\u002Fammin\u002FAM35\u002FAM35_59.pdf' class='refpdflink'>\u003C\u002Fa>",{"id":194,"year":195,"html":196,"doi":11},1118652,1951,"Palache, Charles; Berman, Harry; Frondel, Clifford (1951) \u003Ci>The System of Mineralogy\u003C\u002Fi> (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.",{"id":198,"year":199,"html":200,"doi":201},3015,1979,"Moore, Paul B., Ito, Jun (1979) Alluaudites, wyllieites, arrojadites: crystal chemistry and nomenclature. \u003Ci>Mineralogical Magazine\u003C\u002Fi>,  43 (326) 227-235 \u003Ca target='_blank' href='https:\u002F\u002Fdoi.org\u002F10.1180\u002Fminmag.1979.043.326.04'>doi:10.1180\u002Fminmag.1979.043.326.04\u003C\u002Fa> \u003Ca target='_blank' href='https:\u002F\u002Frruff.info\u002Fdoclib\u002FMinMag\u002FVolume_43\u002F43-326-227.pdf' class='refpdflink'>\u003C\u002Fa>","10.1180\u002Fminmag.1979.043.326.04",{"id":203,"year":204,"html":205,"doi":11},527674,1981,"Moore, Paul B., Araki, Takaharu, Merlino, Stefano, Mellini, Marcello, Zanazzi, and Pier Francesco (1981) The arrojadite-dickinsonite series, KNa\u003Csub>4\u003C\u002Fsub>Ca(Fe,Mn)\u003Csup>2+\u003C\u002Fsup>\u003Csub>14\u003C\u002Fsub>Al(OH)\u003Csub>2\u003C\u002Fsub>(PO\u003Csub>4\u003C\u002Fsub>)\u003Csub>14\u003C\u002Fsub>: crystal structure and crystal chemistry. \u003Ci>American Mineralogist\u003C\u002Fi>,  66 (9-10) 1034-1049 \u003Ca target='_blank' href='http:\u002F\u002Fwww.minsocam.org\u002Fammin\u002FAM66\u002FAM66_1034.pdf' class='refpdflink'>\u003C\u002Fa>",{"id":207,"year":204,"html":208,"doi":209},199830,"Merlino, S., Mellini, M., Zanazzi, P. F. (1981) Structure of arrojadite, KNa\u003Csub>4\u003C\u002Fsub>CaMn\u003Csub>4\u003C\u002Fsub>Fe\u003Csub>10\u003C\u002Fsub>Al(PO\u003Csub>4\u003C\u002Fsub>)\u003Csub>12\u003C\u002Fsub>(OH,F)\u003Csub>2\u003C\u002Fsub>. \u003Ci>Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry\u003C\u002Fi>,  37 (9) 1733-1736 \u003Ca target='_blank' href='https:\u002F\u002Fdoi.org\u002F10.1107\u002Fs0567740881007012'>doi:10.1107\u002Fs0567740881007012\u003C\u002Fa>","10.1107\u002Fs0567740881007012",{"id":211,"year":212,"html":213,"doi":11},16101411,2002,"Steele, I.M. (2002) Arrojadite: variations in space group and composition based on four new refinements. 18th General Meeting of the International Mineralogical Association, Edinburgh, UK 2002, MO2-117.",{"id":215,"year":216,"html":217,"doi":218},395608,2006,"Camara, F. (2006) The arrojadite enigma: I. A new formula and a new model for the arrojadite structure. \u003Ci>American Mineralogist\u003C\u002Fi>,  91 (8) 1249-1259 \u003Ca target='_blank' href='https:\u002F\u002Fdoi.org\u002F10.2138\u002Fam.2006.2189'>doi:10.2138\u002Fam.2006.2189\u003C\u002Fa> \u003Ca target='_blank' href='https:\u002F\u002Frruff.info\u002Fdoclib\u002Fam\u002Fvol91\u002FAM91_1249.pdf' class='refpdflink'>\u003C\u002Fa>","10.2138\u002Fam.2006.2189",{"id":220,"year":216,"html":221,"doi":222},395609,"Chopin, Christian, Oberti, Roberta, Cámara, Fernando (2006) The arrojadite enigma: II. Compositional space, new members, and nomenclature of the group. \u003Ci>American Mineralogist\u003C\u002Fi>,  91 (8). 1260-1270 \u003Ca target='_blank' href='https:\u002F\u002Fdoi.org\u002F10.2138\u002Fam.2006.2190'>doi:10.2138\u002Fam.2006.2190\u003C\u002Fa>","10.2138\u002Fam.2006.2190",{"id":224,"year":225,"html":226,"doi":227},244613,2015,"Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2014 and 2015. Newsletter No 23. \u003Ci>Mineralogical Magazine\u003C\u002Fi>,  79 (1) 51-58 \u003Ca target='_blank' href='https:\u002F\u002Fdoi.org\u002F10.1180\u002Fminmag.2015.079.1.05'>doi:10.1180\u002Fminmag.2015.079.1.05\u003C\u002Fa>","10.1180\u002Fminmag.2015.079.1.05",{"id":229,"year":230,"html":231,"doi":11},16962973,2022,"(2022) Arrojadite-(KFe). \u003Ci>Handbook of Mineralogy\u003C\u002Fi>. Mineralogical Society of America \u003Ca target='_blank' href='https:\u002F\u002Fwww.handbookofmineralogy.org\u002Fpdfs\u002FArrojadite-KFe.pdf' class='refpdflink'>\u003C\u002Fa>",[233,242],{"id":234,"source_url":235,"license_code":236,"credit_html":237,"title":238,"description":239,"author":240,"original_width":241,"original_height":241},1943,"https:\u002F\u002Fcommons.wikimedia.org\u002F?curid=1955913","Public domain","Dave Dyet http:\u002F\u002Fwww.shutterstone.com http:\u002F\u002Fwww.dyet.com, via \u003Ca href=\"https:\u002F\u002Fcommons.wikimedia.org\u002F?curid=1955913\" rel=\"noopener\">Wikimedia Commons\u003C\u002Fa>","Arrojadite Dodium Plate Mine Keystone South Dakota 2030.jpg","\u003Cp>\u003Cb>\u003Ca href=\"\u002F\u002Fcommons.wikimedia.org\u002Fwiki\u002FCategory:Arrojadite\" title=\"Category:Arrojadite\">Arrojadite\u003C\u002Fa>\u003C\u002Fb>.\n\u003C\u002Fp>\n\u003Cul>\u003Cli>From Dodium Plate Mine, Keystone, Pennington County, \u003Ca href=\"\u002F\u002Fcommons.wikimedia.org\u002Fwiki\u002FSouth_Dakota\" class=\"mw-redirect\" title=\"South Dakota\">South Dakota\u003C\u002Fa>.\u003C\u002Fli>\u003C\u002Ful>\n\u003Cdiv style=\"clear:both;\">\u003C\u002Fdiv>\n\u003Cul>\u003Cli>\u003Ci>These mineral images are free to use how you wish.\u003C\u002Fi>\u003C\u002Fli>\u003C\u002Ful>","Dave Dyet http:\u002F\u002Fwww.shutterstone.com http:\u002F\u002Fwww.dyet.com",700,{"id":243,"source_url":244,"license_code":245,"credit_html":246,"title":247,"description":248,"author":249,"original_width":250,"original_height":251},1944,"https:\u002F\u002Fcommons.wikimedia.org\u002F?curid=10122226","CC BY-SA 3.0","Robert M. Lavinsky, via \u003Ca href=\"https:\u002F\u002Fcommons.wikimedia.org\u002F?curid=10122226\" rel=\"noopener\">Wikimedia Commons\u003C\u002Fa>","Arrojadite-(KFe)-24761.jpg","\u003Ca href=\"https:\u002F\u002Fen.wikipedia.org\u002Fwiki\u002FArrojadite-(KFe)\" class=\"extiw\" title=\"en:Arrojadite-(KFe)\">Arrojadite-(KFe)\u003C\u002Fa>\n\u003Cdl>\u003Cdd>\u003Cdl>\u003Cdd>Locality: \u003Ca href=\"https:\u002F\u002Fen.wikipedia.org\u002Fwiki\u002FRapid_Creek\" class=\"extiw\" title=\"en:Rapid Creek\">Rapid Creek\u003C\u002Fa>, Dawson Mining District, \u003Ca href=\"https:\u002F\u002Fen.wikipedia.org\u002Fwiki\u002FYukon\" class=\"extiw\" title=\"en:Yukon\">Yukon Territory\u003C\u002Fa>, Canada (\u003Ca rel=\"nofollow\" class=\"external text\" href=\"http:\u002F\u002Fwww.mindat.org\u002Floc-630.html\">Locality at mindat.org\u003C\u002Fa>)\u003C\u002Fdd>\n\u003Cdd>A solid plate with sharp chocolatey xls to 6mm. EXCEPTIONAL FOR THE SPECIES! These are from a find of 3 years ago and are among the richest examples of the species recovered. this is a solid plate, that can even be broken up into many equally good reference specimens. 4 x 3.5 x 0.75 cm\u003C\u002Fdd>\u003C\u002Fdl>\u003C\u002Fdd>\u003C\u002Fdl>","Robert M. Lavinsky",289,375,[253,259,265],{"id":254,"url":255,"label":256,"formula":257,"spacegroup":258,"year":204},990,"\u002Fcif\u002F990.cif","Moore 1981","Al Fe14 Ca Na4 K P12 O48 F2","A 1 2\u002Fa 1",{"id":260,"url":261,"label":262,"formula":263,"spacegroup":264,"year":204},992,"\u002Fcif\u002F992.cif","Merlino 1981","Ca Na4.11 K.75 Li.12 Mg.5 Fe9.38 Mn4 Al P12 O50 H2","C 1 2\u002Fc 1",{"id":266,"url":267,"label":268,"formula":269,"spacegroup":270,"year":199},993,"\u002Fcif\u002F993.cif","Krutik 1979","Fe12 Mn2 Al Na2.25 K.25 Ba.25 Sr.25 Ca P12 O46.68 F3.32 H1.32","B 1 1 2\u002Fb",[272,273,274,275,276,277,278,279],"Arrojadiet-(KFe)","Arrojadit","Arrojadita","Arrojaditt-(KFe)","Arrojardit","Headdenit","Headdenita","Headdenite",[281,286,290,294],{"lang":282,"names":283},"ca",[284,285],"Arrojadita-","arrojadita-(KFe)",{"lang":287,"names":288},"de",[289],"Arrojadit-(KFe)",{"lang":291,"names":292},"eu",[284,293],"Arrojadita-(KFe)",{"lang":295,"names":296},"it",[297,298,7],"Arrojadite","Arrojadite-","Q3623861",{"history":11,"applications":11}]