Arsmirandite

Na18Cu12Fe3+O8(AsO4)8Cl5
IMA status
  • Approved
IMA symbol
Asm
IMA approved
2014
Also known as
  • Arsmirandiet
  • Arsmiranditt
  • IMA2014-081

Where it forms, where it's found

Geological setting

Volcanic fumarole.

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Translucent · Opaque
Colour
Dark greyish green to olive-greenish black

Translucent only in thin sections.

Streak
Greyish green with an olive hue.
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.715 g/cm³

Optical

Pleochroism
Not Visible
Optical colour
Dark gray
Anisotropism
Very weak.
Bireflectance
Very weak.
Tropism
Anisotropic
Reflectance R%
(7.2,7.5) 400, (7.4,7.7) 420, (7.4,7.7) 440, (7.3,7.6) 460, (7.3,7.6) 470, (7.2,7.5) 480, (7.1,7.4) 500, (7.0,7.3) 520, (6.9,7.2) 540, (6.9,7.2) 546, (6.9,7.1) 560, (6.8,7.1) 580, (6.8,7.1) 589, (6.8,7.0) 600, (6.7,7.0) 620, (6.7,7.0) 640, (6.7,7.0) 650, (6.7,6.9) 660, (6.7,6.9) 680, (6.7,6.9) 700
Reflected-light panel
7.0 %anisotropic · dual curve
Specimen sRGB 100, 68, 36
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Very weak.
Anisotropism
Very weak.
Reflected colour
Dark gray

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 10.742(2) Å · b = 21.019(3) Å · c = 11.787(2) Å
Cell angles
β = 117.06(3) °
Ratio a:b:c
1 : 1.957 : 1.097
Unit cell volume
2370 ų
Morphology

Individual crystals are equant, thick tabular or short prismatic, with pyramid-like terminations.

Twinning

Cyclic interpenetration twins, similar to phillipsite.

Parting
None observed.
Type-locality form

Equant crystals, up to 20 × 20 × 30 sq. μm, usually intergrown to form thin crusts, up to 2 × 3 cm in area.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper1263.546762.552
28.79%
8OOxygenOxygen4015.999639.960
24.16%
33AsArsenicArsenic874.922599.376
22.63%
11NaSodiumSodium1822.990413.820
15.62%
17ClChlorineChlorine535.450177.250
6.69%
26FeIronIron155.84555.845
2.11%
Total2648.803100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Arsmirandiet
  • Arsmiranditt
  • IMA2014-081

In other languages

German
Arsmirandit · IMA 2014-081
Italian
arsmirandite

Classification

Strunz
10th ed.

8.BK.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BKWith medium-sized and large cations, (OH, etc.):RO4 = 2:1, 2.5:1Group
  • 8.BK.35ArsmiranditeSpecies

Literature, links & citation

Citations
  1. 2015Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2014 and 2015. Newsletter No 23. Mineralogical Magazine, 79 (1) 51-58 doi:10.1180/minmag.2015.079.1.05DOI: 10.1180/minmag.2015.079.1.05
  2. 2020Pekov, I.V., Britvin, S.N., Yapaskurt, V.O., Koshlyakova, N.N., Polekhovsky, Yu.S., Göttlicher, J., Chukanov, N.V., Vigasina, M.F., Krivovichev, S.V., Turhkova, A.G., Sidorov, E.G. (2020) Arsmirandite, Na18Cu12Fe3+O8(AsO4)8Cl5, and lehmannite, Na18Cu12TiO8(AsO4)8FCl5, new minerals from fumerole exhalations of the Tolbachik Volcano, Kamchatka, Russia. Zapiski RMO, 149. 1-17
  3. 2020Britvin, S. N., Pekov, I. V., Yapaskurt, V. O., Koshlyakova, N. N., Göttlicher, J., Krivovichev, S. V., Turchkova, A. G., Sidorov, E. G. (2020). Polyoxometalate chemistry at volcanoes: discovery of a novel class of polyoxocuprate nanoclusters in fumarolic minerals. Scientific Reports: 10(1): 1-7.
  4. 2022(2022) Arsmirandite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Arsmirandite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/arsmirandite-46530},
  note      = {Accessed 2026-05-11}
}