Artsmithite

Hg1+4Al(PO4)1.74(OH)1.78
IMA status
  • Approved
IMA symbol
Ash
IMA approved
2002
Also known as
  • Artsmithiet
  • Artsmithitt
  • IMA2002-039

Where it forms, where it's found

Geological setting

Fracture filling in Jackfork sandstone with other mercury minerals; likely a product of breakdown of primary cinnabar and apatite.

Type locality
Funderburk prospect
  1. Pike County
  2. Arkansas
  3. USA

34.1770°, -93.6590°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent
Colour
Colorless
Streak
Off white to cream
Tenacity
flexible
Cleavage
None Observed

needles are flexible

Fracture
Irregular/Uneven
Density
6.40 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 60°
Principal indices
n >1.80
Birefringence
Very low.
Dispersion
Distinct, r < v.
Extinction
Parallel extinction; length-slow with Z ≈ c.
UV response
None.

Crystallography

Crystal system
Monoclinic
Space group
#10
Cell parameters
a = 17.022 Å · b = 9.074 Å · c = 7.015 Å
Cell angles
β = 101.2 °
Ratio a:b:c
1 : 0.533 : 0.412
Unit cell volume
1062.9 ų
Z
4
Type-locality form

Matted nest (3 x 1 mm) of fibrous to acicular crystals, 0.5 mm in length on average; the length-to-width ratio is over 100:1.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
80HgMercuryMercury4200.592802.368
78.29%
8OOxygenOxygen8.7415.999139.831
13.64%
15PPhosphorusPhosphorus1.7430.97453.895
5.26%
13AlAluminiumAluminium126.98226.982
2.63%
1HHydrogenHydrogen1.781.0081.794
0.18%
Total1024.870100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Artsmithiet
  • Artsmithitt
  • IMA2002-039

In other languages

German
Artsmithit · IMA 2002-039
Italian
Artsmithite
Chinese
磷铝汞石

Classification

Strunz
10th ed.

8.BO.40

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BOWith only large cations, (OH, etc.):RO4 about 1:1Group
  • 8.BO.40ArtsmithiteSpecies

Literature, links & citation

Citations
  1. 2003Roberts, A. C., Cooper, M. A., Hawthorne, F. C., Gault, R. A., Grice, J. D., Nikischer, A. J. (2003) Arytsmithite, a new Hg1+-Al phosphate-hydroxide from the Funderburk Prospect, Pike County, Arkansas, U.S.A. The Canadian Mineralogist, 41 (3) 721-725 doi:10.2113/gscanmin.41.3.721 DOI: 10.2113/gscanmin.41.3.721
  2. 2004Jambor, J.L., Roberts, A.C. (2004) New mineral names. American Mineralogist: 89: 249-253.
  3. 2021(2021) Artsmithite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Artsmithite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/artsmithite-26878},
  note      = {Accessed 2026-05-11}
}