Avdoninite

K2Cu5Cl8(OH)4 · 2H2O
IMA status
  • Approved
IMA symbol
Avn
IMA approved
2005
Also known as
  • Avdoniniet
  • Avdoninitt
  • IMA2005-046a

Where it forms, where it's found

Geological setting

Volcanic fumarole

Type locality
Yadovitaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.8333°, 160.3333°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Green
Streak
Pale green
Tenacity
brittle
Cleavage
Perfect

on (100)

Fracture
Step-Like
Density
3.03 g/cm³

Optical

Optical type
Biaxial · 2V measured = 90°
Refractive index
1.669 – 1.707
Surface relief
High
Principal indices
nα 1.669 · nβ 1.688 · nγ 1.707
Michel-Lévy diagramhighlighted lineδ = 0.0380
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]380 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation380 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 11.592(2) Å · b = 6.5509(11) Å · c = 11.745(2) Å
Cell angles
β = 91.104(6) °
Ratio a:b:c
1 : 0.565 : 1.013
Unit cell volume
891.8 ų
Z
2
Morphology

short-prismatic to thick tabular crystals

Type-locality form

Imperfect, short-prismatic, partly flattened crystals up to 0.2 mm in length in aggregates, and in pseudomorphs after melanothallite

Comment

From Pekov et al. (2015).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper563.546317.730
40.55%
17ClChlorineChlorine835.450283.600
36.19%
8OOxygenOxygen615.99995.994
12.25%
19KPotassiumPotassium239.09878.196
9.98%
1HHydrogenHydrogen81.0088.064
1.03%
Total783.584100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Avdoniniet
  • Avdoninitt
  • IMA2005-046a

In other languages

German
Avdoninit · IMA 2005-046a
Italian
avdoninite

Classification

Strunz
10th ed.

3.DA.55

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DAWith Cu, etc., without PbGroup
  • 3.DA.55AvdoniniteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1998Bushmakin, A.F., Bazhenova, L.F. (1998) Avdoninite, new mineral from technogene zone of Urals pyrite deposits. In: Ural'skiy mineralogicheskiy sbornik, N8 (Urals mineralogical collection, N 8), Rossiyskaya Akademiya Nauk, Ural'skoye Otdeleniye, Institut Mineralogii. Miass, Russian Federation, pp. 32-39.
  2. 2004Kahlenberg, Volker (2004) On the Crystal Structure of K2Cu5Cl8(OH)4·2H2O. Zeitschrift für anorganische und allgemeine Chemie, 630. 900-903 doi:10.1002/zaac.200400029DOI: 10.1002/zaac.200400029
  3. 2006Chukanov, N.V., Murashko, M.N., Zadov, A.E., Bushmakin, A.F. (2006) Avdoninite, K2Cu5Cl8(OH)4•H2O, a new mineral from volcanic exhalations and from the zone of technogenesis at massive sulphide ore deposits. Proceedings of the Russian Mineralogical Society: 135(3): 38–42.
  4. 2007(2007) New Minerals From Former Soviet Union Countries 1998-2006. Mineralogical Almanac Vol. 11
  5. 2007Chukanov, N. V., Murashko, M. N., Zadov, A. E., Bushmakin, A. F. (2007) Avdoninite, K2Cu5Cl8(OH)4 · H2O, a new mineral species from volcanic exhalations and the technogenic zone at volcanic-hosted massive sulfide deposits. Geology of Ore Deposits, 49 (7) 505-508 doi:10.1134/s1075701507070021DOI: 10.1134/s1075701507070021
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Avdoninite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/avdoninite-27388},
  note      = {Accessed 2026-05-11}
}