Avogadrite

KBF4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Avg
Discovered
1926
Also known as
  • Avogadritt
  • Avogadroit

Where it forms, where it's found

Geological setting

Sublimation products around volcanic fumaroles

Volcanic fumaroles

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
2recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
Colourless to white · yellowish to reddish when impure · colourless in transmitted light
Density
2.9 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 75° · 2V calc = 58°
Refractive index
1.3239 – 1.3247
Surface relief
Low
Principal indices
nα 1.3239 · nβ 1.3245 · nγ 1.3247
Dispersion
r > v, strong
Michel-Lévy diagramhighlighted lineδ = 0.0008
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]8 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation8 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 8.6588 Å · b = 5.48 Å · c = 7.0299 Å
Ratio a:b:c
1 : 0.633 : 0.812
Z
4
Morphology

Octagonal crystals, tabular to platy on (001), may be elongated along [010] or [100].

Type-locality form

minute octagonal crystals and dense crusts

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
9FFluorineFluorine418.99875.992
60.36%
19KPotassiumPotassium139.09839.098
31.05%
5BBoronBoron110.81010.810
8.59%
Total125.900100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Avogadritt
  • Avogadroit

In other languages

German
Avogadrit
Spanish
Avogadrita
Italian
Avogadrite
Japanese
アボガドロ石
Chinese
氟硼钾石
Russian
Авогадрит

Classification

Strunz
10th ed.

3.CA.10

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CABorofluoridesGroup
  • 3.CA.10AvogadriteSpecies
Dana
8th ed.

11.02.02.01

  • 11Halide ComplexesClass
  • 11.02AmBX4Type
  • 11.02.02— unnamed intermediate level —Group
  • 11.02.02.01AvogadriteSpecies
CIM

8.12.2

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.12— unnamed intermediate level —Group
  • 8.12.2AvogadriteSpecies

Literature, links & citation

Citations
  1. 1926Carobbi (1926) Reale accademia nazionale dei Lincei, Rome, Rend.: (6), 4, 382.
  2. 1926Zambonini (1926) Reale accademia nazionale dei Lincei, Rome, Rend.: (6), 3, 644.
  3. 1926Zambonini and Coniglio (1926) Reale accademia nazionale dei Lincei, Rome, Rend.: (6), 3, 521.
  4. 1927American Mineralogist (1927) 12, 232.
  5. 1930Pesce (1930) Gazzetta chimica italiana, Rome: 60: 936.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Avogadrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/avogadrite-438},
  note      = {Accessed 2026-05-11}
}