Bakakinite

Ca2V2O7
IMA status
  • Approved
IMA symbol
Bkkn
IMA approved
2022
Also known as
  • Bakakiniet
  • IMA2022-046

Where it forms, where it's found

Geological setting

high-temperature (not lower than 500ºC) exhalations

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
colourless or pale yellow
Streak
white
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.463 g/cm³

Optical

Pleochroism
Not Visible
Optical colour
grey
Anisotropism
very weak
Bireflectance
weak
Tropism
Anisotropic
Reflectance R%
(15.3,14.4) 470, (14.3,12.8) 546, (14.8,13.6) 589, (14.9,13.9) 650
Notes

The new mineral is transparent and optically anisotropic, however, its optical studies were carried out in reflected light due to high refractive indices. The mean refractive index calculated based on the Gladstone-Dale equation is 1.93.

Reflected-light panel
14.8 %anisotropic · dual curve
Specimen sRGB 144, 98, 54
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
weak
Anisotropism
very weak
Reflected colour
grey

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 6.6241(4) Å · b = 6.9231(5) Å · c = 7.0050(4) Å
Cell angles
α = 86.885(7) ° · β = 63.696(6) ° · γ = 83.300(7) °
Ratio a:b:c
1 : 1.045 : 1.058
Z
2
Parting
none
Type-locality form

flattened crystals up to 30 × 5 μm, typically distorted.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen715.999111.993
38.09%
23VVanadiumVanadium250.942101.884
34.65%
20CaCalciumCalcium240.07880.156
27.26%
Total294.033100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bakakiniet
  • IMA2022-046

In other languages

German
Bakakinit · IMA 2022-046

Classification

Strunz
10th ed.

8.FA

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.FPolyphosphates, Polyarsenates, [4]-PolyvanadatesDivision
  • 8.FAPolyphosphates, etc., without OH and H2O; dimers of corner-sharing RO4 tetrahedra.Group
  • 8.FABakakiniteSpecies

Literature, links & citation

Citations
  1. 2022Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 69. European Journal of Mineralogy, 34 (5) 463-468 doi:10.5194/ejm-34-463-2022 DOI: 10.5194/ejm-34-463-2022
  2. 2023Pekov, Igor V., Agakhanov, Atali A., Koshlyakova, Natalia N., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Britvin, Sergey N., Vigasina, Marina F., Turchkova, Anna G., Nazarova, Maria A. (2023) Bakakinite, Ca2V2O7, a new mineral from fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 87 (5) 695-701 doi:10.1180/mgm.2023.42DOI: 10.1180/mgm.2023.42
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bakakinite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bakakinite-470395},
  note      = {Accessed 2026-05-11}
}