Balićžunićite

Bi2O(SO4)2
IMA status
  • Approved
IMA symbol
Bžć
IMA approved
2013
Also known as
  • Balićžunićiet
  • IMA2012-098

Where it forms, where it's found

Geological setting

high-temperature (600<sup>o</sup>C) fumarole (sublimate)

Type locality
La Fossa crater
  1. Vulcano Island
  2. Lipari
  3. Eolie Islands (Aeolian Islands)
  4. Metropolitan City of Messina
  5. Sicily
  6. Italy

38.4034°, 14.9614°

1recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
colourless · white · pale brown
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
None observed
Density
5.911 g/cm³

Optical

Surface relief
Very high
Principal indices
n 2.09
Notes

optical parameters not measured; n value is calculated

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 6.7386(3) Å · b = 11.1844(5) Å · c = 14.1754(7) Å
Cell angles
α = 80.082(2) ° · β = 88.462(2) ° · γ = 89.517(2) °
Ratio a:b:c
1 : 1.660 : 2.104
Unit cell volume
1052.01 ų
Z
6
Morphology

Prismatic and elongated crystals (∼50 μm across and up to 200 μm long).

Parting
not observed
Type-locality form

elongated (along [100]) prisms, ca. ~50 x max. 200 μm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth2208.980417.960
66.76%
8OOxygenOxygen915.999143.991
23.00%
16SSulfurSulfur232.06064.120
10.24%
Total626.071100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Balićžunićiet
  • IMA2012-098

In other languages

German
Balićžunićit · IMA 2012-098
Italian
balićžunićite

Classification

Strunz
10th ed.

7.A0

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.A0— unnamed intermediate level —Group
  • 7.A0BalićžunićiteSpecies

Literature, links & citation

Citations
  1. 1984Jones, W.M. (1984) Equilibrium pressures over the systems bismuth trisulfate-dibismuthmonoxydisulfate and dibismuthmonoxydisulfate-dibismuthdioxymonosulfate. Slow transformation between two crystalline forms of dibismuthmonoxydisulfate. Journal of Chemical Physics: 80: 3408-3419.
  2. 1988Aurivillius, Bengt, Karen, P., Kjekshus, A., Vicentini, G., Zinner, L. B., Lehrich, F., Nielsen, C. J., Powell, D. L., Trætteberg, M. (1988) Pyrolysis Products of Bi2(SO4)3. II. Crystal Structure of Bi2O(SO4)2. Acta Chemica Scandinavica, 42. 95-110 doi:10.3891/acta.chem.scand.42a-0095DOI: 10.3891/acta.chem.scand.42a-0095
  3. 2013Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2013) New minerals and nomenclature modifications approved in 2013. CNMNC Newsletter No 16. Mineralogical Magazine, 77 (6) 2695-2709 doi:10.1180/minmag.2013.077.6.01DOI: 10.1180/minmag.2013.077.6.01
  4. 2014Pinto, D., Garavelli, A., Mitolo, D. (2014) Balićžunićite, Bi2O(SO4)2, a new fumarole mineral from La Fossa crater, Vulcano, Aeolian Islands, Italy. Mineralogical Magazine, 78 (4) 1043-1055 doi:10.1180/minmag.2014.078.4.15 DOI: 10.1180/minmag.2014.078.4.15
  5. 2015Pinto, Daniela, Garavelli, Anna, Balić-Žunić, Tonci (2015) The crystal structure of balićžunićite, Bi2O(SO4)2, a new natural bismuth oxide sulfate. Mineralogical Magazine, 79 (3) 597-611 doi:10.1180/minmag.2015.079.3.06 DOI: 10.1180/minmag.2015.079.3.06
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Balićžunićite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/baliczunicite-43864},
  note      = {Accessed 2026-05-11}
}