Balipholite

LiBaMg2Al3(Si2O6)2(OH)8
IMA status
  • Approved
  • Grandfathered
IMA symbol
Blp
Discovered
1975
Also known as
  • Balipholiet
  • Balipholita

Where it forms, where it's found

Geological setting

In a miarolitic cavity.

Type locality
Xianghualing Mine
  1. Xianghualing Sn-polymetallic ore field
  2. Linwu Co.
  3. Chenzhou
  4. Hunan
  5. China

25.4586°, 112.5672°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Silky
Transparency
Transparent · Translucent
Colour
Pale yellowish-white
Cleavage
Perfect

Perfect on (010), distinct on (100) and (110).

Density
3.32 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 68 – 72° · 2V calc = 58°
Refractive index
1.581 – 1.6008
Surface relief
Moderate
Principal indices
nα 1.581 · nβ 1.5958 · nγ 1.6008
Dispersion
r < v moderate
Michel-Lévy diagramhighlighted lineδ = 0.0198
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]198 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation198 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Ccca
Cell parameters
a = 13.6 Å · b = 20.24 Å · c = 5.16 Å
Ratio a:b:c
1 : 1.488 : 0.379
Z
4
Type-locality form

Crystals needle-like and fibrous.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2015.999319.980
44.80%
56BaBariumBarium1137.327137.327
19.23%
14SiSiliconSilicon428.085112.340
15.73%
13AlAluminiumAluminium326.98280.946
11.33%
12MgMagnesiumMagnesium224.30548.610
6.81%
1HHydrogenHydrogen81.0088.064
1.13%
3LiLithiumLithium16.9406.940
0.97%
Total714.207100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Fe
  • Mn
  • Be
  • Ca
  • Na
  • K
  • P

Synonyms

  • Balipholiet
  • Balipholita

In other languages

German
Balipholit
Italian
Balifolite · Balipholite
Russian
балифолит

Classification

Strunz
10th ed.

9.DB.05

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DBInosilicates with 2-periodic single chains, Si2O6; Pyroxene-related mineralsGroup
  • 9.DB.05BalipholiteSpecies
Dana
8th ed.

65.01.05.04

  • 65Inosilicates Single-width, Unbranched Chains, (w=1)Class
  • 65.01Single-Width Unbranched Chains, W=1 with chains P=2Type
  • 65.01.05Carpholite groupGroup
  • 65.01.05.04BalipholiteSpecies
CIM

16.12.11

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.12Aluminosilicates of Sr, Ba and ZnGroup
  • 16.12.11BalipholiteSpecies

Literature, links & citation

Citations
  1. 1975X-ray Laboratory, Wuhan Geologic College; Geology Team 654, Hunan Geology Bureau; and Geology Laboratory, Hunan Geology Bureau (1975): A new lithium-bearing mineral in China-Balipholite, BaMg2LiAl3[Si2O6]2(OH)8. Scientia Geologica Sinica, 1975(1), 100-100. (in Chinese with English abstract).
  2. 1975X-ray Laboratory, Wuhan Geologic College; Geology Team 654, Hunan Geology Bureau; and Geology Laboratory, Hunan Geology Bureau (1975): A new lithium-bearing mineral in China-Balipholite, BaMg2LiAl3[Si2O6]2(OH)8. Scientia Geologica Sinica 1975(1), 100 (in Chinese with English abstract).
  3. 1976Fleischer, Michael, Chao, George Y., Mandarino, Joseph A. (1976) New Mineral Names. American Mineralogist, 61 (3-4) 338-341
  4. 1977X-ray Laboratory, Wuhan Geologic College, Geology Laboratory, Hunan Geology Bureau, Geology Team 654, Hunan Geology Bureau (1977) Balipholite BaMg2LiAl3[Si2O6]2(OH, F)8 and its crystal structure. Scientia Geologica Sinica, 1977(1), 65-82.
  5. 1987Peng, Z., Ma, Z., Han, S. (1987) The refinement of the crystal structure of balipholite. Scientia Sinica, Series B, 30, 779-784.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Balipholite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/balipholite-495},
  note      = {Accessed 2026-05-11}
}