Barberiite

(NH4)BF4
IMA status
  • Approved
IMA symbol
Bbi
Discovered
1994
Also known as
  • Barberiiet
  • IMA1993-008

Where it forms, where it's found

Geological setting

Sublimates in active fumaroles

Type locality
La Fossa crater
  1. Vulcano Island
  2. Lipari
  3. Eolie Islands (Aeolian Islands)
  4. Metropolitan City of Messina
  5. Sicily
  6. Italy

38.4034°, 14.9614°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Colourless
Streak
White
Density
1.89 g/cm³

Optical

Optical type
Biaxial · 2V measured = 90°
Surface relief
Low
Principal indices
n 1.3081
Dispersion
r > v, strong

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 9.0615 Å · b = 5.6727 Å · c = 7.2672 Å
Ratio a:b:c
1 : 0.626 : 0.802
Z
4
Morphology

Commonly in globular aggregates; rarely as pseudohexagonal crystals, tabular to platy on (001), typically elongated along [010] or [100]

Type-locality form

Globular aggregates to 2 mm, rarely as pseudohexagonal platy crystals to 300 µm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
9FFluorineFluorine418.99875.992
72.48%
7NNitrogenNitrogen114.00714.007
13.36%
5BBoronBoron110.81010.810
10.31%
1HHydrogenHydrogen41.0084.032
3.85%
Total104.841100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • K
  • Na

Synonyms

  • Barberiiet
  • IMA1993-008

In other languages

German
Barberiit · IMA 1993-008
Italian
Barberiite

Classification

Strunz
10th ed.

3.CA.10

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CABorofluoridesGroup
  • 3.CA.10BarberiiteSpecies
Dana
8th ed.

11.02.04.01

  • 11Halide ComplexesClass
  • 11.02AmBX4Type
  • 11.02.04— unnamed intermediate level —Group
  • 11.02.04.01BarberiiteSpecies

Literature, links & citation

Citations
  1. 1971Caron, A.P. and Ragle, J.L. (1971) Refinement of the structure of orthorhombic ammonium tetrafluoroborate, NH4BF4. Acta Crystallographica: 27: 1102-1107.
  2. 1994Garavelli, Anna, Vurro, Filippo (1994) Barberiite, NH4BF4 a new mineral from Vulcano, Aeolian Islands, Italy. American Mineralogist, 79 (3-4) 381-384
  3. 1997Anthony, J.W., et al. (1997) Handbook of Mineralogy, Vol. 3: 38.
  4. 2005(2005) Barberiite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2005Zelenski, Michael, Bortnikova, Svetlana (2005) Sublimate speciation at Mutnovsky volcano, Kamchatka. European Journal of Mineralogy, 17 (1) 107-118 doi:10.1127/0935-1221/2005/0017-107DOI: 10.1127/0935-1221/2005/0017-107
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Barberiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/barberiite-513},
  note      = {Accessed 2026-05-11}
}