Barquillite

Cu2(Cd,Fe)GeS4
IMA status
  • Approved
IMA symbol
Bql
Also known as
  • Barquilliet
  • IMA1996-050

Where it forms, where it's found

Geological setting

In a hydrothermal Sn–Ge–Cd–Cu–Fe vein deposit.

Type locality
Fuentes Villanas Mine
  1. Barquilla Sn-Ge-Cd-Cu-Fe Deposit
  2. Villar de la Yegua
  3. Salamanca
  4. Castile and Leon
  5. Spain

Safety & handling

Physical

Hardness
123456789104 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Cleavage
None Observed
Density
4.53 g/cm³

Optical

Pleochroism
Weak
Optical colour
Gray with a violet tint
Anisotropism
Very weak
Bireflectance
Very weak
Tropism
Anisotropic
Reflectance R%
(24.8) 400, (24.8) 420, (24.7) 440, (24.4) 460, (24.2) 480, (23.8) 500, (23.5) 520, (23.3) 540, (23.2) 560, (23.0) 580, (23.1) 600, (23.1) 620, (23.3) 640, (23.5) 660, (23.3) 680, (22.9) 700
Reflected-light panel
23.7 %isotropic · single curve
Specimen sRGB 176, 123, 69
White reference100 % reflector under same lamp
Bireflectance
Very weak
Anisotropism
Very weak
Reflected colour
Gray with a violet tint

Crystallography

Crystal system
Tetragonal
Space group
I-4 2m
Cell parameters
a = 5.45(4) Å · c = 10.61(1) Å
Z
2
Type-locality form

Platy crystals, to 50 μm, commonly in rosette-like aggregates.

Comment

sp. gr. by analogy to briartite

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
16SSulfurSulfur432.060128.240
25.84%
29CuCopperCopper263.546127.092
25.61%
48CdCadmiumCadmium1112.414112.414
22.65%
32GeGermaniumGermanium172.63072.630
14.64%
26FeIronIron155.84555.845
11.26%
Total496.221100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ag
  • Zn
  • Fe
  • Mn
  • Sn
  • Ga
  • Sb
  • Bi

Synonyms

  • Barquilliet
  • IMA1996-050

In other languages

German
Barquillit · IMA 1996-050
Spanish
Barquillita
Italian
Barquillite

Classification

Strunz
10th ed.

2.KA.10

  • 2Sulfides and SulfosaltsClass
  • 2.KSulfarsenates, SulfantimonatesDivision
  • 2.KASulfarsenates with (As,Sb)S4 tetrahedraGroup
  • 2.KA.10BarquilliteSpecies

Literature, links & citation

Citations
  1. 1990Babkine, J., Dusausoy, Y, Murciego, A., Gonzalo Corral, F.J. (1990) Un nouveau sulfure cadmifere, Cu2CdGeS4, apparenté à la briartite, de la mine Barquilla (Espagne). Bulletin de liaison de la Société française de minéralogie et de cristallographie, 2(1), 47.
  2. 1999Jambor, J.L., Roberts, A.C. (1999) New mineral names. American Mineralogist: 84: 1464-1468.
  3. 1999Murciego, Ascensión, Pascua, Ma Inmaculada, Babkine, Jean, Dusausoy, Yves, Medenbach, Olaf, Bernhardt, Hans-Jürgen (1999) Barquillite, Cu2(Cd, Fe)GeS4, a new mineral from the Barquilla deposit, Salamanca, Spain. European Journal of Mineralogy, 11 (1) 111-118 doi:10.1127/ejm/11/1/0111DOI: 10.1127/ejm/11/1/0111
  4. 2021(2021) Barquillite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Barquillite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/barquillite-6820},
  note      = {Accessed 2026-05-11}
}