Barrotite

Cu9Al(HSiO4)2[(SO4)(HAsO4)0.5](OH)12 · 8H2O
IMA status
  • Approved
IMA symbol
Bro
IMA approved
2011
Also known as
  • Barrotiet
  • IMA2011-063a

Where it forms, where it's found

Geological setting

In sandstone.

Type locality
Roua Mines (Clue de Roua)
  1. Daluis
  2. Nice Arrondissement
  3. Alpes-Maritimes
  4. Provence-Alpes-Côte d'Azur
  5. France

44.0304°, 6.8677°

3recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Intense blue
Streak
Pale blue
Tenacity
flexible
Cleavage
Perfect

Micaceous cleavage on (001)

Fracture
Irregular/Uneven
Density
2.90 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.576 – 1.652
Surface relief
Moderate
Principal indices
nω 1.652 · nε 1.576
Pleochroism
Visible

ω=blue ε=light blue

UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0760
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]760 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation760 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Trigonal
Cell parameters
a = 10.650(2) Å · c = 21.954(7) Å
Unit cell volume
2156.5 ų
Z
3
Morphology

Hexagonal, tabular on (001). Forms (001) and (110).

Twinning

Twinning not observed.

Type-locality form

Perfect hexagonal plates of maximum size 0.5x0.02 mm or grouped in aggregates to 2 mm in size.

Comment

Space Group P31 or P32

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper963.546571.914
44.02%
8OOxygenOxygen3415.999543.966
41.86%
14SiSiliconSilicon228.08556.170
4.32%
33AsArsenicArsenic0.574.92237.461
2.88%
16SSulfurSulfur132.06032.060
2.47%
1HHydrogenHydrogen30.51.00830.744
2.37%
13AlAluminiumAluminium126.98226.982
2.08%
Total1299.297100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Barrotiet
  • IMA2011-063a

In other languages

German
Barrotit · IMA 2011-063a
Italian
barrotite

Classification

Strunz
10th ed.

7.DE.45

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DEWith only medium-sized cations; unclassifiedGroup
  • 7.DE.45BarrotiteSpecies

Literature, links & citation

Citations
  1. 2013Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2013) New minerals and nomenclature modifications approved in 2013. CNMNC Newsletter No 16. Mineralogical Magazine, 77 (6) 2695-2709 doi:10.1180/minmag.2013.077.6.01DOI: 10.1180/minmag.2013.077.6.01
  2. 2014Sarp H., Cerny R., Puscharovsky D.Yu., Schouwink P., Teyssier J., Williams P.A., Babalik H., Mari G. (2014): La barrotite, Cu9Al(HSiO4)2[(SO4)(HAsO4)0.5](OH)12•8H2O, un nouveau minéral de la mine de Roua (Alpes-Maritimes, France). Riviera Scientifique, 98, 3-22.
  3. 2022(2022) Barrotite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Barrotite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/barrotite-43860},
  note      = {Accessed 2026-05-11}
}