Bassanite

Ca(SO4) · 0.5H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bss
Discovered
1910
Also known as
  • Bassaniet
  • Hemihydrate
  • Miltonit
  • +11 more

Where it forms, where it's found

Geological setting

In cavities of leucite-tephrite blocks ejected from an active volcano.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
114recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent · Translucent · Opaque
Colour
White
Streak
White
Density
2.69 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.55 – 1.57
Surface relief
Moderate
Principal indices
nω 1.55 · nε 1.57
Michel-Lévy diagramhighlighted lineδ = 0.0200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]200 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation200 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#7
Cell parameters
a = 12.0317(4) Å · b = 6.9269(2) Å · c = 12.6712(3) Å
Cell angles
β = 90.27(1) °
Ratio a:b:c
1 : 0.576 : 1.053
Z
12
Morphology

Needlelike crystals, often in parallel aggregates.

Twinning

About [010], twin plane (101), may be sectored.

Type-locality form

White, opaque crystals to 1 cm, as pseudomorphs after gypsum.

Comment

Space group I2 (non-standard setting)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4.515.99971.996
49.60%
20CaCalciumCalcium140.07840.078
27.61%
16SSulfurSulfur132.06032.060
22.09%
1HHydrogenHydrogen11.0081.008
0.70%
Total145.142100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bassaniet
  • Hemihydrate
  • Miltonit
  • Miltonita
  • Miltonite
  • Mirupolskit
  • Mirupolskita
  • Mirupolskite
  • Plaster of Paris
  • Polyhydrate
  • Soluble Anhydrite
  • Vibertit
  • Vibertita
  • Vibertite

In other languages

French
bassanite · hémihydrate · miltonite · mirupolskite · polyhydrate · vibertite
German
Bassanit · Elektrikergips · Gebrannter Gips · Halbhydrat · Hemihydrat
Spanish
Bassanita
Italian
bassanite
Chinese
燒石膏

Classification

Strunz
10th ed.

7.CD.45

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CDWith only large cationsGroup
  • 7.CD.45BassaniteSpecies
Dana
8th ed.

29.06.01.01

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.06AXO4·xH2OType
  • 29.06.01— unnamed intermediate level —Group
  • 29.06.01.01BassaniteSpecies
CIM

25.4.2

  • 25SulphatesClass
  • 25.4Sulphates of Ca, Sr and BaGroup
  • 25.4.2BassaniteSpecies

Literature, links & citation

Citations
  1. 1910Zambonini, F. (1910) Mineralogia Vesuviana. Bassanite CaSO4. Atti della Reale Accademia delle Scienze Fisiche e Matematiche di Napoli, Serie II: 14: 327-328.
  2. 1933Gallitelli, P. (1933) Ricerche sul solfato di calcio semidrato e sull’anidrite solubile. Periodico di Mineralogia: 4: 132-171.
  3. 1933Gaubert, P. (1933) Sur l'hémihydrate de sulfate de calcium et ses produits de deshydratation. Comptes rendus de l’Académie des sciences de Paris: 197: 72-75.
  4. 1936Caspari, W.A. (1936) Calcium sulphate hemihydrate and anhydrites. I - Crystallography. Proceedings of the Royal Society of London: 155A: 41-48.
  5. 1946Berg and Sveshnikova (1946) Bulletin de Académy des sciences de l'Union des Républiques Soviétiques Socialistes, Cl. sc. mat. nat., Ser. chim.: No. 1: 19.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bassanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bassanite-557},
  note      = {Accessed 2026-05-11}
}