Batoniite

Al8(SO4)5(OH)14(H2O)18 · 5H2O
IMA status
  • Approved
IMA symbol
Bato
IMA approved
2023
Also known as
  • Batoniiet
  • IMA2023-008

Where it forms, where it's found

Geological setting

action of H2SO4 on Al-bearing rocks of Paleozoic age

Type locality
Le Cetine di Cotorniano mine
  1. Chiusdino
  2. Siena Province
  3. Tuscany
  4. Italy

43.2320°, 11.1683°

2recorded occurrences
Source · OpenStreetMap

Physical

Colour
white to colorless
Streak
white
Tenacity
very brittle
Cleavage
Perfect

shows a (011) perfect cleavage; there are other less distinct cleavage surfaces, but their crystallographic orientation was not determined.

Density
1.949 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 71° · 2V calc = 75.8°
Refractive index
1.4833 – 1.5019
Surface relief
Low
Principal indices
nα 1.4833 · nβ 1.4948 · nγ 1.5019
UV response
none
Michel-Lévy diagramhighlighted lineδ = 0.0186
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]186 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation186 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 9.1757(6) Å · b = 12.0886(9) Å · c = 20.9218(15) Å
Cell angles
α = 82.901(3) ° · β = 87.334(3) ° · γ = 86.999(2) °
Ratio a:b:c
1 : 1.317 : 2.280
Unit cell volume
2295.7 ų
Z
2
Type-locality form

hemispherical aggregates composed of brittle tabular crystals, up to 1 mm in size

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen5715.999911.943
67.62%
13AlAluminiumAluminium826.982215.856
16.01%
16SSulfurSulfur532.060160.300
11.89%
1HHydrogenHydrogen601.00860.480
4.48%
Total1348.579100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Batoniiet
  • IMA2023-008

In other languages

German
Batoniit
Italian
Batoniite

Classification

Strunz
10th ed.

7.DA

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DAWith small cationsGroup
  • 7.DABatoniiteSpecies

Literature, links & citation

Citations
  1. 2023Bosi, Ferdinando; Hatert, Frédéric; Pasero, Marco; Mills, Stuart J. (2023) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 73. European Journal of Mineralogy, 35 (3). 397-402 doi:10.5194/ejm-35-397-2023 DOI: 10.5194/ejm-35-397-2023
  2. 2023Mauro, Daniela, Biagioni, Cristian, Sejkora, Jiří, Dolníček, Zdeněk, Škoda, Radek (2023) Batoniite, [Al8(OH)14(H2O)18](SO4)5  ⋅  5H2O, a new mineral with the [Al8(OH)14(H2O)18]10+ polyoxocation from the Cetine di Cotorniano Mine, Tuscany, Italy. European Journal of Mineralogy, 35 (5) 703-714 doi:10.5194/ejm-35-703-2023 DOI: 10.5194/ejm-35-703-2023
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Batoniite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/batoniite-470773},
  note      = {Accessed 2026-05-11}
}