Bernalite

Fe(OH)3
IMA status
  • Approved
IMA symbol
Bnl
Discovered
1992
Also known as
  • Bernaliet
  • IMA1991-032

Where it forms, where it's found

Geological setting

On a museum specimen from a metamorphosed Pb-Zn deposit, probably from the surface oxidation zone

Type locality
Broken Hill
  1. Broken Hill district
  2. Yancowinna Co.
  3. New South Wales
  4. Australia
11recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Opaque
Colour
Dark bottle-green to yellow-green · yellowish bottle-green in thin section
Streak
Apple-green
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven · Conchoidal
Density
3.32 g/cm³

Optical

Optical type
Biaxial
Surface relief
Very high
Principal indices
n 1.92 – 1.94
Dispersion
r > v, strong

Crystallography

Crystal system
Orthorhombic
Space group
#69
Cell parameters
a = 7.544 Å · b = 7.56 Å · c = 7.558 Å
Ratio a:b:c
1 : 1.002 : 1.002
Z
8
Morphology

Flattened pyramidal crystals, pseudo-octahedral to pseudo-cubic, with slightly concave faces; also skeletal aggregates.

Twinning

Polysynthetic, crosshatched, observed in thin section, probably pinacoidal.

Type-locality form

Flattened pyramidal crystals and pseudo-octahedra, to 3 mm.

Comment

Pseudocubic. Originally described with space group Immm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron155.84555.845
52.26%
8OOxygenOxygen315.99947.997
44.91%
1HHydrogenHydrogen31.0083.024
2.83%
Total106.866100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • C
  • Pb
  • Si
  • Zn

Synonyms

  • Bernaliet
  • IMA1991-032

In other languages

German
Bernalit · Eisen(III)-hydroxid · IMA 1991-032
Italian
Bernalite
Chinese
伯纳尔石

Classification

Strunz
10th ed.

4.FC.05

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FCHydroxides with OH, without H2O; corner-sharing octahedraGroup
  • 4.FC.05BernaliteSpecies
Dana
8th ed.

06.03.05.03

  • 06Hydroxides and Oxides Containing HydroxylClass
  • 06.03X(OH)3Type
  • 06.03.05Dzhalindite GroupGroup
  • 06.03.05.03BernaliteSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. 1992Birch, W. D., Pring, A., Reller, A., Schmalle, H. (1992) Bernalite: a new ferric hydroxide with perovskite structure. Naturwissenschaften, 79 (11). 509-511 doi:10.1007/bf01135768DOI: 10.1007/bf01135768
  2. 1993Birch, William D., Pring, Allan, Reller, Armin, Schmalle, Helmut W. (1993) Bernalite, Fe(OH)3, a new mineral from Broken Hill, New South Wales: Description and structure. American Mineralogist, 78 (7-8) 827-834
  3. 1995McCammon, C.A., Pring, A., Keppler, H., Sharp, T. (1995) A study of bernalite, Fe(OH)3, using Mössbauer spectroscopy, optical spectroscopy and transmission electron microscopy. Physics and Chemistry of Minerals, 22 (1). 11-20 doi:10.1007/bf00202676DOI: 10.1007/bf00202676
  4. 1997Anthony, John Williams, Bideaux, Richard A., Bladh, Kenneth W., Nichols, Monte C. - Ed. (1997) Handbook of Mineralogy Vol. 3 - Halides, Hydroxides, Oxides. Mineral Data Publishing, Tucson, Arizona. p.1-682.
  5. 1998Kolitsch, U. (1998) Bernalite from the Clara mine, Germany, and the incorporation of tungsten in minerals containing ferric iron. The Canadian Mineralogist, 36 (5). 1211-1216
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bernalite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bernalite-635},
  note      = {Accessed 2026-05-11}
}