Birchite

Cd2Cu2(PO4)2(SO4) · 5H2O
IMA status
  • Approved
IMA symbol
Bc
IMA approved
2006
Also known as
  • Birchiet
  • Birchitt
  • IMA2006-048

Where it forms, where it's found

Geological setting

Secondary mineral formed under late stage supergene low-temperature conditions.

Type locality
Broken Hill
  1. Broken Hill district
  2. Yancowinna Co.
  3. New South Wales
  4. Australia
1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Pale blue
Tenacity
brittle
Cleavage
None Observed
Fracture
Conchoidal
Density
3.61 g/cm³

Optical

Optical type
Biaxial (+) · 2V calc = 63°
Refractive index
1.624 – 1.669
Surface relief
Moderate
Principal indices
nα 1.624 · nβ 1.636 · nγ 1.669
Pleochroism
Weak

Very faint pleochroism. X = pale bluish, Z = pale greenish.

Dispersion
No or only very small dispersion.
Extinction
X = b; Y = a; Z = c.
UV response
Not fluorescent.
Notes

Absorption: Z ≥ X.

Michel-Lévy diagramhighlighted lineδ = 0.0450
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]450 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation450 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 10.489(6) Å · b = 20.901(7) Å · c = 6.155(5) Å
Ratio a:b:c
1 : 1.993 : 0.587
Unit cell volume
1349.6 ų
Z
4
Morphology

Crystals are bladed (somewhat lath-shaped) and prismatic to acicular in habit. Elongated along [001] and sometimes also flattened on (100). Main forms are (100) and (010). Most crystals are not well terminated, but some show minor (101) and (001) faces.

Twinning

No twinning observed.

Type-locality form

Sprays and aggregates to crystals to 0.75 mm. Individual crystals are bladed to prismatic and acicular, with a max. length of 0.3 mm and width of 0.05 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
37.36%
48CdCadmiumCadmium2112.414224.828
30.88%
29CuCopperCopper263.546127.092
17.46%
15PPhosphorusPhosphorus230.97461.948
8.51%
16SSulfurSulfur132.06032.060
4.40%
1HHydrogenHydrogen101.00810.080
1.39%
Total727.991100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Birchiet
  • Birchitt
  • IMA2006-048

In other languages

German
Birchit · IMA 2006-048
Italian
birchite
Chinese
水硫磷铜镉石

Classification

Strunz
10th ed.

8.DB.70

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DBWith only medium-sized cations, (OH, etc.):RO4< 1:1Group
  • 8.DB.70BirchiteSpecies
Dana
8th ed.

43.03.03

  • 43Compound Phosphates, Etc.Class
  • 43.03Hydrated Normal Compound Phosphates, etc·Type
  • 43.03.03— unnamed intermediate level —Group
  • 43.03.03BirchiteSpecies

Literature, links & citation

Citations
  1. 2008Elliott, P., Brugger, J., Pring, A., Cole, M. L., Willis, A. C., Kolitsch, U. (2008) Birchite, a new mineral from Broken Hill, New South Wales, Australia: Description and structure refinement. American Mineralogist, 93 (5) 910-917 doi:10.2138/am.2008.2732 DOI: 10.2138/am.2008.2732
  2. 2021(2021) Birchite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Birchite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/birchite-35925},
  note      = {Accessed 2026-05-11}
}