Brassite

Mg(AsO3OH) · 4H2O
IMA status
  • Approved
IMA symbol
Bsi
Discovered
1973
Also known as
  • Brassiet
  • IMA1973-047

Where it forms, where it's found

Geological setting

Post-mine alteration of arsenic ore.

Type locality
Jáchymov
  1. Karlovy Vary District
  2. Karlovy Vary Region
  3. Czech Republic

50.3661°, 12.9233°

12recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Translucent
Colour
White
Streak
White
Tenacity
brittle
Cleavage
Perfect

(001) perfect.

Fracture
Irregular/Uneven · Splintery
Density
2.28 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.531 – 1.562
Surface relief
Moderate
Principal indices
nα 1.531 · nβ 1.546 · nγ 1.562
Birefringence
0.031
Pleochroism
Non-pleochroic
Dispersion
r < v moderate
Extinction
XYZ=bac; 2V=very large
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0310
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]310 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation310 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pbca
Cell parameters
a = 7.472 Å · b = 10.891 Å · c = 16.585 Å
Ratio a:b:c
1 : 1.458 : 2.220
Z
8
Type-locality form

crusts of fine grained material

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen815.999127.992
54.17%
33AsArsenicArsenic174.92274.922
31.71%
12MgMagnesiumMagnesium124.30524.305
10.28%
1HHydrogenHydrogen91.0089.072
3.84%
Total236.291100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Brassiet
  • IMA1973-047

In other languages

French
brassite
German
Brassit · IMA 1973-047
Spanish
Brassita
Italian
Brassite
Chinese
水砷镁石
Arabic
براسيت

Classification

Strunz
10th ed.

8.CE.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CEWith only medium-sized cations, RO4:H2O about 1:2.5Group
  • 8.CE.15BrassiteSpecies
Dana
8th ed.

39.01.07.01

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.01A[HXO4]·xH2OType
  • 39.01.07— unnamed intermediate level —Group
  • 39.01.07.01BrassiteSpecies
CIM

20.2.2

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.2Arsenates of Be, Mg, Ca or BaGroup
  • 20.2.2BrassiteSpecies

Literature, links & citation

Citations
  1. 1973Fontan, François, Orliac, Marcel, Permingeat, François, Pierrot, Roland, Stahl, Réjane (1973) La brassite, MgHAsO4 • 4H2O, une nouvelle espèce minérale. Bulletin de Minéralogie, 96 (6) 365-370 doi:10.3406/bulmi.1973.6850 DOI: 10.3406/bulmi.1973.6850
  2. 1975Fleischer, Michael; Mandarino, Joseph A. (1975) New mineral names. American Mineralogist, 60 (9-10). 945-947
  3. 1976Protas, J., Gindt, R. (1976) Structure cristalline de la brassite, MgHAsO4.4H2O, produit de déshydratation de la roesslérite. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 32 (5) 1460-1466 doi:10.1107/s0567740876005566DOI: 10.1107/s0567740876005566
  4. 2005(2005) Brassite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2009Frost, Ray L., Bahfenne, Silmarilly, Čejka, Jiří, Sejkora, Jiří, Palmer, Sara J., Škoda, Radek (2009) Raman microscopy of haidingerite Ca(AsO3OH)·H2O and brassite Mg(AsO3OH)·4H2O. Journal of Raman Spectroscopy, 41 (6). 690-693 doi:10.1002/jrs.2498DOI: 10.1002/jrs.2498
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Brassite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/brassite-756},
  note      = {Accessed 2026-05-11}
}