Brenkite

Ca2(CO3)F2
IMA status
  • Approved
IMA symbol
Bki
Discovered
1977
IMA approved
1977
Also known as
  • Brenkiet
  • IMA1977-036

Where it forms, where it's found

Geological setting

In voids and fissures in a porphryritic selbergite

Type locality
Schellkopf
  1. Brenk
  2. Brohltal
  3. Ahrweiler
  4. Rhineland-Palatinate
  5. Germany

50.4321°, 7.1645°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Colorless
Streak
White
Cleavage
None Observed
Density
3.10 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 26 – 28° · 2V calc = 22°
Refractive index
1.525 – 1.593
Surface relief
Moderate
Principal indices
nα 1.525 · nβ 1.59 · nγ 1.593
Dispersion
r > v
Extinction
X = a; Y = a.
Michel-Lévy diagramhighlighted lineδ = 0.0680
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]680 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation680 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pbcn
Cell parameters
a = 7.650(4) Å · b = 7.550(2) Å · c = 6.548(2) Å
Ratio a:b:c
1 : 0.987 : 0.856
Z
4
Morphology

Lath-like crystals showing forms (010), (110), (102), and (021).

Type-locality form

Prismatic crystals

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
20CaCalciumCalcium240.07880.156
44.99%
8OOxygenOxygen315.99947.997
26.94%
9FFluorineFluorine218.99837.996
21.33%
6CCarbonCarbon112.01112.011
6.74%
Total178.160100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Brenkiet
  • IMA1977-036

In other languages

German
Brenkit · IMA 1977-036
Italian
Brenkite

Classification

Strunz
10th ed.

5.BC.05

  • 5CarbonatesClass
  • 5.BCarbonates with additional anions, without H2ODivision
  • 5.BCWith alkali-earth cationsGroup
  • 5.BC.05BrenkiteSpecies
Dana
8th ed.

16a.03.06.01

  • 16aAnhydrous Carbonates Containing Hydroxyl or HalogenClass
  • 16a.03(AB)2(XO3)ZqType
  • 16a.03.06— unnamed intermediate level —Group
  • 16a.03.06.01BrenkiteSpecies
CIM

12.1.6

  • 12Carbonates with other anionsClass
  • 12.1Carbonates with halidesGroup
  • 12.1.6BrenkiteSpecies

Literature, links & citation

Citations
  1. 1978Hentschel, G., Leufer, U., Tillmanns, E. (1978): Brenkit, ein neues Kalzium-Fluor-Carbonat von Schellkopf, Eifel. Neues Jahrbuch für Mineralogie, Monatshefte, 1978, 325-329.
  2. 1979Fleischer, Michael, Chao, George Y., Pabst, and Adolf (1979) New Mineral Names. American Mineralogist, 64 (1-2) 241-245
  3. 1980Leufer, U., Tillmanns, E. (1980) Die Kristallstruktur von Brenkit, Ca2F2CO3. TMPM Tschermaks Mineralogische und Petrographische Mitteilungen, 27 (4). 261-266 doi:10.1007/bf01159264DOI: 10.1007/bf01159264
  4. 2005(2005) Brenkite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Brenkite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/brenkite-764},
  note      = {Accessed 2026-05-11}
}