Brezinaite

Cr3S4
IMA status
  • Approved
IMA symbol
Bzn
Discovered
1969
IMA approved
1969
Also known as
  • Brezianit
  • Brezinaiet
  • IMA1969-004

Where it forms, where it's found

Geological setting

Iron meteorite.

Meteorite

Type locality
Tucson meteorite (Irwin-Ainsa meteorite)
  1. Box Canyon
  2. Pima County
  3. Arizona
  4. USA

31.8500°, -110.9667°

9recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Density
4.12 g/cm³

Optical

Optical colour
Brownish gray
Tropism
Anisotropic
Notes

Reflectivity 37-40%; very similar to daubreelite.

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 5.96(1) Å · b = 3.425(5) Å · c = 11.270(15) Å
Cell angles
β = 91.53 °
Ratio a:b:c
1 : 0.575 : 1.891
Z
2
Morphology

Anhedral grains to 3mm

Twinning

Polysynthetic. Most commonly seen as two sets of lamallae almost at right angles. Sometimes a third set of more irregular twins is observed to intersect the first two at an oblique angle.

Type-locality form

Tiny (5-80 micron) anhedral grains in nickel-iron matrix and contiguous to silicate inclusions.

Comment

Space Group: I2/m (synthetic)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
24CrChromiumChromium351.996155.988
54.88%
16SSulfurSulfur432.060128.240
45.12%
Total284.228100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • V
  • Ti
  • Mn
  • Ni

Synonyms

  • Brezianit
  • Brezinaiet
  • IMA1969-004

In other languages

German
Brezinait · IMA 1969-004
Italian
brezinaite

Classification

Strunz
10th ed.

2.DA.15

  • 2Sulfides and SulfosaltsClass
  • 2.DMetal Sulfides, M: S = 3 :4 and 2:3Division
  • 2.DAM:S = 3:4Group
  • 2.DA.15BrezinaiteSpecies
Dana
8th ed.

02.10.02.02

  • 02SulfidesClass
  • 02.10AmBnXp, with (m+n):p = 3:4Type
  • 02.10.02Wilkmanite GroupGroup
  • 02.10.02.02BrezinaiteSpecies
CIM

3.8.1

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.8Sulphides etc. of Cr, Mo, W an MnGroup
  • 3.8.1BrezinaiteSpecies

Literature, links & citation

Citations
  1. 1957Jellinek, F. (1957) The structures of the chromium sulphides. Acta Crystallographica, 10 (10) 620-628 doi:10.1107/s0365110x57002200DOI: 10.1107/s0365110x57002200
  2. 1969Bunch, T. E., Fuchs, Louis H. (1969) A new mineral: Brezinaite, Cr3S4, and the Tucson meteorite. American Mineralogist, 54 (11-12) 1509-1518
  3. 1971Igaki, Kenzo; Ohashi, Nobumitsu; Mikami, Masao (1971) Phase Relation of Nonstoichiometric Chromium Sulfide CrSx in the Range of 1.200 < x < 1.480. Journal of the Physical Society of Japan: 31(5): 1424-1430.
  4. 1993Davis, D.E. (1993) Brezinaite revisited. Meteoritics: 28(3): 339.
  5. 2005(2005) Brezinaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Brezinaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/brezinaite-768},
  note      = {Accessed 2026-05-11}
}