Brianite

Na2CaMg(PO4)2
IMA status
  • Approved
IMA symbol
Bne
Discovered
1966
IMA approved
1966
Also known as
  • Brianiet
  • IMA1966-030

Where it forms, where it's found

Geological setting

Meteorite

Type locality
Dayton meteorite
  1. Dayton
  2. Montgomery County
  3. Ohio
  4. USA

39.7500°, -84.1667°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless
Density
3.00 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 63 – 65° · 2V calc = 66°
Refractive index
1.598 – 1.608
Surface relief
Moderate
Principal indices
nα 1.598 · nβ 1.605 · nγ 1.608
Birefringence
0.010
Pleochroism
Non-pleochroic
Dispersion
r < v weak
Extinction
extinction ^ lamellae = 2-3°
Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 13.36 Å · b = 5.23 Å · c = 9.13 Å
Cell angles
β = 91.2 °
Ratio a:b:c
1 : 0.391 : 0.683
Type-locality form

Granular with lamellar structure.

Comment

Am Min (1975) 60:717; ICDD 29-1192

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen815.999127.992
42.62%
15PPhosphorusPhosphorus230.97461.948
20.63%
11NaSodiumSodium222.99045.980
15.31%
20CaCalciumCalcium140.07840.078
13.35%
12MgMagnesiumMagnesium124.30524.305
8.09%
Total300.303100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Brianiet
  • IMA1966-030

In other languages

French
Brianite
German
Brianit · IMA1966-030
Spanish
Brianita
Italian
Brianite

Classification

Strunz
10th ed.

8.AC.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.30BrianiteSpecies
Dana
8th ed.

38.01.07.01

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.01ABXO4Type
  • 38.01.07— unnamed intermediate level —Group
  • 38.01.07.01BrianiteSpecies
CIM

19.4.9

  • 19PhosphatesClass
  • 19.4Phosphates of CaGroup
  • 19.4.9BrianiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1967Fuchs, Louis H., Olsen, E., Henderson, E.P. (1967) On the occurrence of brianite and panethite, two new phosphate minerals from the Dayton meteorite. Geochimica et Cosmochimica Acta, 31 (10) 1711-1719 doi:10.1016/0016-7037(67)90118-4DOI: 10.1016/0016-7037(67)90118-4
  2. 1968Fleischer, Michael (1968) New Mineral Names. American Mineralogist, 53 (3-4) 507-511
  3. 1975Moore, Paul Brian (1975) Brianite, Na2CaMg[PO4]2: A phosphate analog of merwinite, Ca2CaMg[SiO4]2. American Mineralogist, 60 (7-8) 717-718
  4. 1998Alkemper, J.; Fuess, H. (1998) The crystal structures of NaMgPO4, Na2CaMg(PO4)2 and Na18Ca13Mg5(PO4)18: new examples for glaserite related structures. Zeitschrift für Kristallographie, 213 (5). 282-287 doi:10.1524/zkri.1998.213.5.282 DOI: 10.1524/zkri.1998.213.5.282
  5. 2005(2005) Brianite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Brianite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/brianite-771},
  note      = {Accessed 2026-05-11}
}