Brizziite

NaSbO3
IMA status
  • Approved
IMA symbol
Bzi
IMA approved
1993
Also known as
  • Brizziiet
  • Brizzite

Where it forms, where it's found

Geological setting

Weathering product of stibnite in an antimony deposit in highly silicified limestone.

Type locality
Le Cetine di Cotorniano mine
  1. Chiusdino
  2. Siena Province
  3. Tuscany
  4. Italy

43.2320°, 11.1683°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Pearly
Transparency
Transparent
Colour
Colourless · light pink or yellow in aggregates
Streak
White
Tenacity
elastic
Cleavage
Perfect

on (0001)

Density
4.8 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.631 – 1.84
Surface relief
High
Principal indices
nω 1.84 · nε 1.631
Michel-Lévy diagramhighlighted lineδ = 0.2090
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2090 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2090 nm
Order4th order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#80
Cell parameters
a = 5.301 Å · c = 15.932 Å
Z
6
Morphology

Hexagonal crystals, flattened on (0001), in dense aggregates and incrustations.

Twinning

On (0001), polysynthetic, common.

Type-locality form

Dense aggregates and incrustations of platy hexagonal crystals to 0.2 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
51SbAntimonyAntimony1121.760121.760
63.17%
8OOxygenOxygen315.99947.997
24.90%
11NaSodiumSodium122.99022.990
11.93%
Total192.747100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Brizziiet
  • Brizzite

In other languages

German
Brizziit · IMA 1993-044
Spanish
Brizziíta
Italian
Brizziite · Brizziite-III · Brizziite-VII
Chinese
锑钠石

Classification

Strunz
10th ed.

4.CB.05

  • 4OxidesClass
  • 4.CMetal: Oxygen = 2: 3,3: 5, and similarDivision
  • 4.CBWith medium-sized cationsGroup
  • 4.CB.05BrizziiteSpecies
Dana
8th ed.

44.03.12.01

  • 44AntimonatesClass
  • 44.03MiscellaneousType
  • 44.03.12— unnamed intermediate level —Group
  • 44.03.12.01BrizziiteSpecies

Literature, links & citation

Citations
  1. 1938Schrewelius, N. (1938): Röntgenuntersuchung der Verbindungen NaSb(OH)6, NaSb6, NaSbO3 und gleichartiger Stoffe. Zeitschrift für Anorganische und Allgemeine Chemie, 238, 241-254.
  2. 1994Sabelli, C., Olmi, F. and Santucci, A. (1994): Brizziite, una nuova specie da Le Cetine di Cotorniano (SI). Rivista Mineralogica Italiana, 1994, 271-273 (in Italian).
  3. 1994Olmi, Filippo, Sabelli, Cesare (1994) Brizziite, NaSbO3, a new mineral from the Cetine mine (Tuscany, Italy): description and crystal structure. European Journal of Mineralogy, 6 (5) 667-672 doi:10.1127/ejm/6/5/0667 DOI: 10.1127/ejm/6/5/0667
  4. 1995Jambor, J.L., Kovalenker, V.A., Roberts, A.C. (1995) New mineral names. American Mineralogist, 80, 630-635.
  5. 1997Anthony, J. W. et al. (1997): Handbook of Mineralogy, Vol. 3, 77.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Brizziite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/brizziite-778},
  note      = {Accessed 2026-05-11}
}