Brüggenite

Ca(IO3)2 · H2O
IMA status
  • Approved
IMA symbol
Brü
IMA approved
1970
Also known as
  • Brüggeniet
  • IMA1970-040

Where it forms, where it's found

Geological setting

Nitrate deposit

Type locality
Pampa del Pique III
  1. Oficina Lautaro
  2. Taltal
  3. Antofagasta Province
  4. Antofagasta
  5. Chile
2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Colorless to bright yellow.
Streak
(not reported)
Tenacity
brittle
Cleavage

None

Fracture
Conchoidal
Density
4.24 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 86 – 96° · 2V calc = 86°
Refractive index
1.7755 – 1.8205
Surface relief
High
Principal indices
nα 1.7755 · nβ 1.7985 · nγ 1.8205
Dispersion
r < v strong
Luminescence
Nonfluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0450
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]450 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation450 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 8.509(1) Å · b = 10.027(2) Å · c = 7.512(1) Å
Cell angles
β = 95.267 °
Ratio a:b:c
1 : 1.178 : 0.883
Z
4
Morphology

Crystals subhedral, to 1 cm, short prismatic, elongated along [001], with (010) and (011), other faces irregular, and a diamond-shaped cross-section showing (320).

Type-locality form

In radiating clusters and long columnar anhedral crystals, intergrown with nitratine; as crusts.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
53IIodineIodine2126.904253.808
62.22%
8OOxygenOxygen715.999111.993
27.46%
20CaCalciumCalcium140.07840.078
9.83%
1HHydrogenHydrogen21.0082.016
0.49%
Total407.895100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Brüggeniet
  • IMA1970-040

In other languages

German
Brüggenit · IMA 1970-040
Italian
Brüggenite

Classification

Strunz
10th ed.

4.KC.10

  • 4OxidesClass
  • 4.KIodates: Trigonal [IO3] pyramids (mostly).Division
  • 4.KCIodates without additional anions, with H2OGroup
  • 4.KC.10BrüggeniteSpecies
Dana
8th ed.

21.01.02.01

  • 21Normal IodatesClass
  • 21.01MiscellaneousType
  • 21.01.02— unnamed intermediate level —Group
  • 21.01.02.01BrüggeniteSpecies
CIM

29.4

  • 29IodatesClass
  • 29.4— unnamed intermediate level —Group
  • 29.4BrüggeniteSpecies

Literature, links & citation

Citations
  1. 1971Mrose, M.E., Ericksen, G.E., Marinenko, J.W. (1971) Brüggenite, Ca(IO3)2·H2O, a new saline mineral from the Chilean nitrate deposits. Program and Abstracts, 20th Clay Minerals Conference: 20: 13-13.
  2. 1971Mrose, M.E., Ericksen, G.E., Marinenko, J.W. (1971) Crystal chemistry of the calcium iodates in the system Ca(IO3)2-H2O. Geological Society of America, Abstracts Annual Meetings: 1971: 653-653.
  3. 1972Fleischer, Michael (1972) New Mineral Names. American Mineralogist, 57 (3-4) 594-598
  4. 1972Fleischer, M. (1972) New Mineral Names. American Mineralogist, 57 (11-12). 1909-1914
  5. 1974Ericksen, G.E., Mrose, M.E., Marinenko, J.W. (1974) Mineralogical studies of the nitrate deposits of Chile. IV. Brüggenite, Ca(IO3)2·H2O, a new saline mineral. Journal of Research of the United States Geological Survey: 2: 471-478.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Brüggenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bruggenite-769},
  note      = {Accessed 2026-05-11}
}