Bubnovaite

K2Na8Ca(SO4)6
IMA status
  • Approved
IMA symbol
Bub
IMA approved
2015
Also known as
  • Bubnovaiet
  • IMA2014-108

Where it forms, where it's found

Geological setting

In volcanic fumaroles of the 2012-2013 Tolbachik Fissure Eruption, Tolbachik volcano (Naboko cone), Kamchatka Peninsula, Russia. The temperature of gases at the sampling location was more than 500 °C.

Type locality
Naboko cinder cone
  1. Great Fissure eruption (Main Fracture)
  2. Tolbachik Volcanic field
  3. Milkovsky District
  4. Kamchatka Krai
  5. Russia

55.7683°, 160.3164°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Light-blue · colorless
Streak
White
Tenacity
brittle
Density
2.656 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.489 – 1.492
Surface relief
Low
Principal indices
nω 1.492 · nε 1.489
Pleochroism
Non-pleochroic
Michel-Lévy diagramhighlighted lineδ = 0.0030
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]30 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation30 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
P3 1c
Cell parameters
a = 10.804(3) Å · c = 22.011(6) Å
Unit cell volume
2225 ų
Z
4
Morphology

needle-like, tabular

Type-locality form

Aggregates of needles or tablets.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
43.71%
16SSulfurSulfur632.060192.360
21.90%
11NaSodiumSodium822.990183.920
20.93%
19KPotassiumPotassium239.09878.196
8.90%
20CaCalciumCalcium140.07840.078
4.56%
Total878.530100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mg
  • Cu
  • (Zn, Pb)

Synonyms

  • Bubnovaiet
  • IMA2014-108

In other languages

German
Bubnovait · IMA 2014-108
Italian
bubnovaite

Classification

Strunz
10th ed.

7.AD

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ADWith only large cationsGroup
  • 7.ADBubnovaiteSpecies

Literature, links & citation

Citations
  1. 2015Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2015, CNMNC Newsletter No 25. Mineralogical Magazine, 79 (3) 529-535 doi:10.1180/minmag.2015.079.3.02DOI: 10.1180/minmag.2015.079.3.02
  2. 2016Gorelova, Liudmila A., Vergasova, Lidiya P., Krivovichev, Sergey V., Yu. Avdontseva, Evgenia, Moskaleva, Svetlana V., Karpov, Genadii A., Filatov, Stanislav K. (2016) Bubnovaite, K2 Na8 Ca(SO4)6, a new mineral species with modular structure from the Tolbachik volcano, Kamchatka peninsula, Russia. European Journal of Mineralogy, 28 (3) 677-686 doi:10.1127/ejm/2016/0028-2530DOI: 10.1127/ejm/2016/0028-2530
  3. 2017(2017) Bubnovaite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2023Shablinskii, Andrey P., Filatov, Stanislav K., Biryukov, Yaroslav P. (2023) Crystal structures inherited from parent high-temperature disordered microblocks: Ca2SiO4, Na2SO4–K2SO4 sulfates, and related minerals (bubnovaite and dobrovolskyite) Physics and Chemistry of Minerals, 50 (4) 30 doi:10.1007/s00269-023-01253-6DOI: 10.1007/s00269-023-01253-6
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bubnovaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bubnovaite-46614},
  note      = {Accessed 2026-05-11}
}