Bultfonteinite

Ca2SiO3(OH)F · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bul
Discovered
1932
Also known as
  • Bultfonteiniet

Where it forms, where it's found

Geological setting

a large "horse" of diabase and shale fragments in a kimberlite pipe

Type locality
Bultfontein Mine
  1. KEM JV Mine (Kimberley Ekapa Mining Joint Venture mine
  2. Kimberley Underground mine)
  3. Kimberley
  4. Sol Plaatje Local Municipality
  5. Frances Baard District Municipality
  6. Northern Cape
  7. South Africa

-28.7682°, 24.7921°

20recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
colourless · pink
Streak
white
Cleavage
Distinct/Good

Good on (100) and (010)

Fracture
Conchoidal
Density
2.73 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70°
Refractive index
1.587 – 1.597
Surface relief
Moderate
Principal indices
nα 1.587 · nβ 1.590 · nγ 1.597
Dispersion
r > v
Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 10.99 Å · b = 8.18 Å · c = 5.67 Å
Cell angles
α = 93.95 ° · β = 91.32 ° · γ = 89.85 °
Ratio a:b:c
1 : 0.744 : 0.516
Z
4
Twinning

Interpenetrating on (100) and (010); polysynthetic.

Type-locality form

As radiating prismatic acicular crystals and radial spherules, to 2 cm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
20CaCalciumCalcium240.07880.156
38.12%
8OOxygenOxygen515.99979.995
38.05%
14SiSiliconSilicon128.08528.085
13.36%
9FFluorineFluorine118.99818.998
9.03%
1HHydrogenHydrogen31.0083.024
1.44%
Total210.258100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • B
  • Al
  • Na
  • P

Synonyms

  • Bultfonteiniet

In other languages

French
bultfontéinite
German
Bultfonteinit
Spanish
Bultfonteinita · Bultfonteinite
Italian
bultfonteinite

Classification

Strunz
10th ed.

9.AG.80

  • 9SilicatesClass
  • 9.ANesosilicatesDivision
  • 9.AGNesosilicates with additional anions; cations in > [6] +- [6] coordinationGroup
  • 9.AG.80BultfonteiniteSpecies
Dana
8th ed.

52.04.07.02

  • 52Nesosilicates Insular Sio4 Groups and O, Oh, F, H2oClass
  • 52.04Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] and/or >[6] coordinationType
  • 52.04.07Afwillite and related speciesGroup
  • 52.04.07.02BultfonteiniteSpecies
CIM

17.1.16

  • 17Silicates Containing other AnionsClass
  • 17.1Silicates with fluoride (not containing Al)Group
  • 17.1.16BultfonteiniteSpecies

Literature, links & citation

Citations
  1. 1932Parry, John, Williams, Alpiieus F., Wright, F. E. (1932) On bultfonteinite, a new fluorine-bearing hydrous calcium silicate from South Africa. Mineralogical Magazine and Journal of the Mineralogical Society, 23 (138) 145-162 doi:10.1180/minmag.1932.023.138.01 DOI: 10.1180/minmag.1932.023.138.01
  2. 1933Foshag, W.F. (1933) New mineral names. American Mineralogist: 18: 32-32.
  3. 1955Murdoch, Joseph (1955) Bulfonteinite from Crestmore, California. American Mineralogist, 40 (9-10) 900-904
  4. 1955Megaw, H.D., Kelsey, C.H. (1955) An accurate determination of the cell dimensions of bultfonteinite, Ca4Si2O10H6F2. Mineralogical Magazine: 30: 569-573.
  5. 1963McIver, E.J. (1963) The structure of bultfonteinite. Ca4Si3O10F2H6: Acta Crystallographica: 16: 551-558.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bultfonteinite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bultfonteinite-800},
  note      = {Accessed 2026-05-11}
}