Where it forms, where it's found
- Geological setting
Clinkers formed by the fusion of wood ash in partly burned trees.
- Type locality
- Grand Canyon National Park
- Arizona
- USA
8recorded occurrences
Physical
Optical
- Optical type
- Uniaxial
- Refractive index
- 1.455 – 1.595
- Surface relief
- Moderate
- Principal indices
- nω 1.595 · nε 1.455
- Luminescence
- (not reported)
Δ = 0Δmax
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1400 nm
Order3rd order
XPL colour
Crystallography
- Space group
- #99
- Cell parameters
- a = 5.3822(4) Å · c = 18.156(2) Å
- Z
- 3
- Morphology
Microscopic barrel-shaped crystals elongated [0001], earthy to porcellaneous masses.
- Comment
On synthetic; at 6 GPa transforms to monoclinic (C2/m) phase (Zeff et al. 2024)
Crystal structure
Chemical composition
Synonyms
- Buetschliit
- Buetschliita
- Buetschliite
- Bütschliiet
- Gel-Calcit
In other languages
- German
- Bütschliit
- Italian
- Bütschliite
Classification
Strunz
10th ed.5.AC.15
- 5CarbonatesClass
- 5.ACarbonates without additional anions, without H2ODivision
- 5.ACAlkali and alkali-earth carbonatesGroup
- 5.AC.15BütschliiteSpecies
Dana
8th ed.14.03.01.01
- 14Anhydrous Normal CarbonatesClass
- 14.03A2B(XO3)2Type
- 14.03.01— unnamed intermediate level —Group
- 14.03.01.01BütschliiteSpecies
CIM
—11.1.17
- 11CarbonatesClass
- 11.1Carbonates of the alkali metals and ammoniumGroup
- 11.1.17BütschliiteSpecies
Group, growth & confusion
Literature, links & citation
Citations
- —Zeff, G., Kalkan, B., Armstrong, K., Kunz, M., Williams, Q. (2024): High pressure raman spectroscopy and X-ray diffraction of K2Ca(CO3)2 bütschliite: multiple pressure-induced phase transitions in a double carbonate. Physics and Chemistry of Minerals, 51, 2.
- 1947Milton, Charles, Axelrod, Joseph (1947) Fused wood-ash stones: Fairchildite (n.sp.) K2CO3·CaCO3, buetschliite (n.sp.) 3K2CO3·2CaCO3·6H2O and calcite, CaCO3, their essential components. American Mineralogist, 32 (11-12) 607-624
- 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
- 1958Dawson, Kenneth Ralph; Sabina, Ann P. (1958) A Canadian occurrence of fairchildite and buetschliite [Ontario]. The Canadian Mineralogist, 6 (2). 290-291
- 1965MANDARINO, J.A. & HARRIS, D.C. (1965) New Canadian mineral occurrences. Canadian Mineralogist, 8, 377-381.
Cite this entry
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Bütschliite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/butschliite-821},
note = {Accessed 2026-05-11}
}