Bütschliite

K2Ca(CO3)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Büt
Also known as
  • Buetschliit
  • Buetschliita
  • Buetschliite
  • +2 more

Where it forms, where it's found

Geological setting

Clinkers formed by the fusion of wood ash in partly burned trees.

Type locality
Grand Canyon National Park
  1. Arizona
  2. USA
8recorded occurrences
Source · OpenStreetMap

Physical

Lustre
(not reported)
Transparency
Translucent
Colour
Grayish yellow · brownish gray · may be pale green
Streak
(not reported)
Cleavage
Distinct/Good

Good (?) on (0001)

Density
2.607 g/cm³

Optical

Optical type
Uniaxial
Refractive index
1.455 – 1.595
Surface relief
Moderate
Principal indices
nω 1.595 · nε 1.455
Luminescence
(not reported)
Michel-Lévy diagramhighlighted lineδ = 0.1400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1400 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1400 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#99
Cell parameters
a = 5.3822(4) Å · c = 18.156(2) Å
Z
3
Morphology

Microscopic barrel-shaped crystals elongated [0001], earthy to porcellaneous masses.

Comment

On synthetic; at 6 GPa transforms to monoclinic (C2/m) phase (Zeff et al. 2024)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen615.99995.994
40.28%
19KPotassiumPotassium239.09878.196
32.82%
20CaCalciumCalcium140.07840.078
16.82%
6CCarbonCarbon212.01124.022
10.08%
Total238.290100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Buetschliit
  • Buetschliita
  • Buetschliite
  • Bütschliiet
  • Gel-Calcit

In other languages

German
Bütschliit
Italian
Bütschliite

Classification

Strunz
10th ed.

5.AC.15

  • 5CarbonatesClass
  • 5.ACarbonates without additional anions, without H2ODivision
  • 5.ACAlkali and alkali-earth carbonatesGroup
  • 5.AC.15BütschliiteSpecies
Dana
8th ed.

14.03.01.01

  • 14Anhydrous Normal CarbonatesClass
  • 14.03A2B(XO3)2Type
  • 14.03.01— unnamed intermediate level —Group
  • 14.03.01.01BütschliiteSpecies
CIM

11.1.17

  • 11CarbonatesClass
  • 11.1Carbonates of the alkali metals and ammoniumGroup
  • 11.1.17BütschliiteSpecies

Group, growth & confusion

Often grow together
1 mineral
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Zeff, G., Kalkan, B., Armstrong, K., Kunz, M., Williams, Q. (2024): High pressure raman spectroscopy and X-ray diffraction of K2Ca(CO3)2 bütschliite: multiple pressure-induced phase transitions in a double carbonate. Physics and Chemistry of Minerals, 51, 2.
  2. 1947Milton, Charles, Axelrod, Joseph (1947) Fused wood-ash stones: Fairchildite (n.sp.) K2CO3·CaCO3, buetschliite (n.sp.) 3K2CO3·2CaCO3·6H2O and calcite, CaCO3, their essential components. American Mineralogist, 32 (11-12) 607-624
  3. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  4. 1958Dawson, Kenneth Ralph; Sabina, Ann P. (1958) A Canadian occurrence of fairchildite and buetschliite [Ontario]. The Canadian Mineralogist, 6 (2). 290-291
  5. 1965MANDARINO, J.A. & HARRIS, D.C. (1965) New Canadian mineral occurrences. Canadian Mineralogist, 8, 377-381.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bütschliite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/butschliite-821},
  note      = {Accessed 2026-05-11}
}