Bykovaite

(Ba,Na,K)2(Na,Ti,Mn)4(Ti,Nb)2O2Si4O14(H2O,F,OH)2 · 3.5H2O
IMA status
  • Approved
IMA symbol
Byv
IMA approved
2003
Also known as
  • Bykovaiet
  • IMA2003-044

Where it forms, where it's found

Geological setting

Product of the hydrothermal alteration of bornemanite, in a hyperagpaitic pegmatite

Type locality
Shkatulka pegmatite
  1. Umbozero mine
  2. Alluaiv Mountain
  3. Lovozersky District
  4. Murmansk Oblast
  5. Russia

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Creamy white
Tenacity
brittle
Cleavage
Perfect

on (001), good on (100)

Fracture
Fibrous
Density
2.98 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 63° · 2V calc = 63°
Refractive index
1.668 – 1.71
Surface relief
High
Principal indices
nα 1.668 · nβ 1.679 · nγ 1.71
Pleochroism
Non-pleochroic
Notes

Straight extinction and positive elongation with respect to fiber length. a ≈ Y, b ≈ Z, c ≈ X

Michel-Lévy diagramhighlighted lineδ = 0.0420
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]420 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation420 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 5.552 Å · b = 7.179 Å · c = 50.94 Å
Cell angles
β = 91.1 °
Ratio a:b:c
1 : 1.293 : 9.175
Unit cell volume
2030 ų
Z
4
Type-locality form

compact spherulites, up to 3–5 mm in diameter, and spherulitic aggregates of tiny (0.005–0.05 mm) fibres radiating along [010] from a common centre

Comment

I112/b polytype

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen23.515.999375.976
21.82%
22TiTitaniumTitanium647.867287.202
16.67%
56BaBariumBarium2137.327274.654
15.94%
25MnManganeseManganese454.938219.752
12.75%
41NbNiobiumNiobium292.906185.812
10.78%
11NaSodiumSodium622.990137.940
8.01%
14SiSiliconSilicon428.085112.340
6.52%
19KPotassiumPotassium239.09878.196
4.54%
9FFluorineFluorine218.99837.996
2.21%
1HHydrogenHydrogen131.00813.104
0.76%
Total1722.973100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Ca
  • Fe
  • K
  • Mn
  • Sr

Synonyms

  • Bykovaiet
  • IMA2003-044

In other languages

German
Bykovait · IMA 2003-044
Italian
Bykovaite

Classification

Strunz
10th ed.

9.BE.55

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.55BykovaiteSpecies
Dana
8th ed.

56.02.10.07

  • 56Sorosilicates Si2o7 Groups, with Additional O, Oh, F and H2oClass
  • 56.02Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordinationType
  • 56.02.10Melanotekite groupGroup
  • 56.02.10.07BykovaiteSpecies

Literature, links & citation

Citations
  1. 2005Khomyakov, A.P., Menshikov, Yu.P., Ferraris, G., Nemet, P., Nechelyustov, G.N. (2005) Bykovaite, BaNa{(Na,Ti)4[(Ti,Nb)2(OH,O)3Si4O14](OH,F)2}•3H2O – the new mineral heterophyllosilicate from Lovozero alkaline massif (Kola Peninsula, Russia). Proceedings of the Russian Mineralogical Society: 134(5): 40–48.
  2. 2005Khomyakov, A.P., Menshikov, Yu.P., Ferraris, G., Nemet, P., Nechelyustov, G.N. (2005) Bykovaite, BaNa{(Na,Ti)4[(Ti,Nb)2(OH,O)3Si4O14](OH,F)2}• 3H2O – the new mineral heterophyllosilicate from Lovozero alkaline massif (Kola Peninsula, Russia). Proceedings of the Russian Mineralogical Society: 134(5): 40–48. (Russian with English abstract)
  3. 2005Németh, P. (2005) Characterization of new mineral phases belonging to the heterophyllosilicates series. Plinius, 31. 157-162
  4. 2006Piilonen, P. C.; Rowe, R.; Ercit, T.S.; Locock, A.J. (2006) New Mineral Names. American Mineralogist, 91 (8). 1452-1457 doi:10.2138/am.2006.470 DOI: 10.2138/am.2006.470
  5. 2007(2007) New Minerals From Former Soviet Union Countries 1998-2006. Mineralogical Almanac Vol. 11
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bykovaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bykovaite-26447},
  note      = {Accessed 2026-05-11}
}