Bytownite

(Ca,Na)[Al(Al,Si)Si2O8]
Also known as
  • Bitovnitas
  • Bütauniit
  • Bytowniet
  • +2 more

Where it forms, where it's found

193recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106 – 6.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Colour
Colourless · grey · greenish-white · or white
Streak
White
Cleavage
Perfect

on [001], good on [010]

Fracture
Step-Like

Optical

Optical type
Biaxial (+/-) · 2V measured = 86° · 2V calc = 80 – 88°
Refractive index
1.563 – 1.583
Surface relief
Moderate
Principal indices
nα 1.563 – 1.572 · nβ 1.568 – 1.5784 · nγ 1.573 – 1.583
Dispersion
r > v strong
Luminescence
Non-fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0105
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]105 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation105 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 8.178 Å · b = 12.870 Å · c = 14.187 Å
Cell angles
α = 93.5 ° · β = 115.9 ° · γ = 90.63 °
Ratio a:b:c
1 : 1.574 : 1.735
Z
8
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen815.999127.992
38.87%
14SiSiliconSilicon328.08584.255
25.59%
13AlAluminiumAluminium226.98253.964
16.39%
20CaCalciumCalcium140.07840.078
12.17%
11NaSodiumSodium122.99022.990
6.98%
Total329.279100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Bitovnitas
  • Bütauniit
  • Bytowniet
  • Bytownit
  • Bytownita

Classification

CIM

16.10.1

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.10Aluminosilicates of Ca and alkalisGroup
  • 16.10.1BytowniteSpecies

Literature, links & citation

Citations
  1. 1915Johnston, Robert A. A. (1915) A List of Canadian Mineral Occurrences. Memoir 74. Geological Survey of Canada
  2. 2001(2001) Bytownite. Handbook of Mineralogy. Mineralogical Society of America
  3. 2018Jin, Shiyun; Wang, Xiaoping; Xu, Huifang (2018) Revisiting the I-1 structures of high-temperature Ca-rich plagioclase feldspar – a single-crystal neutron and X-ray diffraction study. Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, 74 (2). 152-164 doi:10.1107/s2052520618003219DOI: 10.1107/s2052520618003219
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bytownite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bytownite-815},
  note      = {Accessed 2026-05-11}
}