Calamaite

Na2TiO(SO4)2 · 2H2O
IMA status
  • Approved
IMA symbol
Clm
IMA approved
2016
Also known as
  • Calamaiet
  • IMA2016-036

Where it forms, where it's found

Geological setting

oxidation zone of a pyrite orebody at a sulfate mine

Type locality
Alcaparrosa Mine
  1. Sierra Gorda
  2. Antofagasta Province
  3. Antofagasta
  4. Chile

-22.6329°, -69.1855°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless (isolated crystals) · white (aggregates)
Tenacity
brittle
Cleavage
Distinct/Good

On (001)

Density
2.45 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 30°
Refractive index
1.557 – 1.671
Surface relief
Moderate
Principal indices
nα 1.557 · nβ 1.562 · nγ 1.671
Michel-Lévy diagramhighlighted lineδ = 0.1140
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1140 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1140 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Ibam
Cell parameters
a = 16.0989(11) Å · b = 16.2399(9) Å · c = 7.0135(4) Å
Ratio a:b:c
1 : 1.009 : 0.436
Unit cell volume
1833.6 ų
Z
8
Morphology

Acicular to 0.01 × 2 mm; rarely prismatic to 1 × 1 × 3 mm

Twinning

Cross-like interpenetration twins are common

Type-locality form

Acicular to hair-like crystals to 2 mm, in bunches or radial spherulitic clusters to 4 mm across. As prismatic crystals and cross-like twins.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1115.999175.989
52.07%
16SSulfurSulfur232.06064.120
18.97%
22TiTitaniumTitanium147.86747.867
14.16%
11NaSodiumSodium222.99045.980
13.61%
1HHydrogenHydrogen41.0084.032
1.19%
Total337.988100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Calamaiet
  • IMA2016-036

In other languages

German
Calamait · IMA 2016-036

Classification

Strunz
10th ed.

7.DF.50

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DF.50CalamaiteSpecies

Literature, links & citation

Citations
  1. 2016Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2016) New minerals and nomenclature modifications approved in 2016, CNMNC Newsletter No. 33. Mineralogical Magazine, 80 (6) 1135-1144 doi:10.1180/minmag.2016.080.085DOI: 10.1180/minmag.2016.080.085
  2. 2018Pekov, Igor V., Siidra, Oleg I., Chukanov, Nikita V., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Turchkova, Anna G., Möhn, Gerhard (2018) Calamaite, a new natural titanium sulfate from the Alcaparrosa mine, Calama, Antofagasta region, Chile. European Journal of Mineralogy, 30 (4) 801-809 doi:10.1127/ejm/2018/0030-2738 DOI: 10.1127/ejm/2018/0030-2738
  3. 2020(2020) Calamaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Calamaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/calamaite-50334},
  note      = {Accessed 2026-05-11}
}