Calcioaravaipaite

PbCa2AlF9
IMA status
  • Approved
IMA symbol
Cavp
IMA approved
1994
Also known as
  • Calcioaravaipaiet
  • IMA1994-018

Where it forms, where it's found

Geological setting

oxidized zone of an epithermal Cu–Pb–Ag deposit

Type locality
Grand Reef Mine
  1. Laurel Canyon
  2. Grand Reef Mountain
  3. Klondyke
  4. Aravaipa Mining District
  5. Graham County
  6. Arizona
  7. USA

32.8825°, -110.3175°

4recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
colorless to white
Streak
white
Tenacity
brittle
Cleavage
Distinct/Good

Good on the (100)

Fracture
Conchoidal
Density
4.85 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 36° · 2V calc = 44°
Refractive index
1.51 – 1.531
Surface relief
Moderate
Principal indices
nα 1.510 · nβ 1.528 · nγ 1.531
Dispersion
r > v strong
Michel-Lévy diagramhighlighted lineδ = 0.0210
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]210 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation210 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#1
Cell parameters
a = 5.3815(3) Å · b = 5.3846(3) Å · c = 12.2034(6) Å
Cell angles
α = 91.362(2) ° · β = 101.110(3) ° · γ = 91.525(3) °
Ratio a:b:c
1 : 1.001 : 2.268
Unit cell volume
346.72 ų
Z
2
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead1207.200207.200
42.69%
9FFluorineFluorine918.998170.982
35.23%
20CaCalciumCalcium240.07880.156
16.52%
13AlAluminiumAluminium126.98226.982
5.56%
Total485.320100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Calcioaravaipaiet
  • IMA1994-018

In other languages

German
Calcioaravaipait · IMA 1994-018
Italian
Calcioaravaipaite

Classification

Strunz
10th ed.

3.AB.37

  • 3HalidesClass
  • 3.ASimple halides, without H2ODivision
  • 3.ABM:X = 1:2Group
  • 3.AB.37CalcioaravaipaiteSpecies

Literature, links & citation

Citations
  1. 1996Foord, Eugene E., Kampf, Anthony R. (1996) Calcioaravaipaite, a New Mineral, and Associated Lead Fluoride Minerals from the Grand Reef Mine, Graham County, Arizona. The Mineralogical Record, 27 (4) 293-300
  2. 1997Mandarino, Joseph A. (1997) Abstracts of New Mineral Descriptions. The Mineralogical Record, 28 (3) 219-224
  3. 2003Kampf, Anthony R., Merlino, Stefano, Pasero, Marco (2003) Order-disorder approach to calcioaravaipaite, [PbCa2Al(F,OH)9]: The crystal structure of the triclinic MDO polytype. American Mineralogist, 88 (2) 430-435 doi:10.2138/am-2003-2-319 DOI: 10.2138/am-2003-2-319
  4. 2005(2005) Calcioaravaipaite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2011Kampf, A. R., Yang, H., Downs, R. T., Pinch, W. W. (2011) The crystal structures and Raman spectra of aravaipaite and calcioaravaipaite. American Mineralogist, 96 (2) 402-407 doi:10.2138/am.2011.3620 DOI: 10.2138/am.2011.3620
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Calcioaravaipaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/calcioaravaipaite-829},
  note      = {Accessed 2026-05-11}
}