Calciolangbeinite

K2Ca2(SO4)3
IMA status
  • Approved
IMA symbol
Clgb
Discovered
2008
IMA approved
2011
Also known as
  • Calciolangbeiniet
  • IMA2011-067

Where it forms, where it's found

Geological setting

Fumarole

Type locality
Yadovitaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.8333°, 160.3333°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Conchoidal
Density
2.68 g/cm³

Optical

Optical type
Isotropic
Surface relief
Moderate
Principal indices
n 1.527
UV response
Not fluorescent
Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.527

Crystallography

Crystal system
Isometric
Space group
#198
Cell parameters
a = 10.1887(2) Å
Z
4
Morphology

Tetrahedral, but when the positive and negative tetrahedron, (111) and {11-1}, are equally developed the habit is pseudo-octahedral. Crystals are typically coarse and/or distorted; they may be flattened, curved or skeletal; some individuals have uneven surfaces.

Parting
Not observed
Type-locality form

Crystals and almost anhedral grains, typically up to 0.5 mm, and rarely up to 1 mm across.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
43.00%
16SSulfurSulfur332.06096.180
21.54%
20CaCalciumCalcium240.07880.156
17.95%
19KPotassiumPotassium239.09878.196
17.51%
Total446.520100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Calciolangbeiniet
  • IMA2011-067

In other languages

German
Calciolangbeinit · IMA 2011-067
Italian
calciolangbeinite

Classification

Strunz
10th ed.

7.AD

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ADWith only large cationsGroup
  • 7.ADCalciolangbeiniteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2011. CNMNC Newsletter No 11. Mineralogical Magazine, 75 (6) 2887-2893 doi:10.1180/minmag.2011.075.6.2887 DOI: 10.1180/minmag.2011.075.6.2887
  2. 2012Pekov, I. V., Zelenski, M. E., Zubkova, N. V., Yapaskurt, V. O., Chukanov, N. V., Belakovskiy, D. I., Pushcharovsky, D. Y. (2012) Calciolangbeinite, K2Ca2(SO4)3, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 76 (3) 673-682 doi:10.1180/minmag.2012.076.3.16 DOI: 10.1180/minmag.2012.076.3.16
  3. 2015(2015) Calciolangbeinite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2022Bulakh, M.O., Pekov, I.V., Koshlyakova, N.N., Britvin, S.N., Nazarova, M.A. (2022) [ Langbeinite-Group Minerals and Vanthoffite from Fumarolic Exhalations of the Tolbachik Volcano (Kamchatka)]. Записки Российского Минералогического Общества [Zapiski RMO (Proceedings of the Russian Mineralogical Society)], 151 (3) 96-122
  5. 2022Pekov, Igor V., Zubkova, Natalia V., Galuskina, Irina O., Kusz, Joachim, Koshlyakova, Natalia N., Galuskin, Evgeny V., Belakovskiy, Dmitry I., Bulakh, Maria O., Vigasina, Marina F., Chukanov, Nikita V., Britvin, Sergey N., Sidorov, Evgeny G., Vapnik, Yevgeny, Pushcharovsky, Dmitry Yu. (2022) Calciolangbeinite-O, a natural orthorhombic modification of K2Ca2(SO4)3, and the langbeinite–calciolangbeinite solid-solution system. Mineralogical Magazine, 86 (4) 557-569 doi:10.1180/mgm.2021.95DOI: 10.1180/mgm.2021.95
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Calciolangbeinite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/calciolangbeinite-42383},
  note      = {Accessed 2026-05-11}
}