Calumetite

Cu4CaCl2(OH)8 · 4H2O
IMA status
  • Approved
IMA symbol
Clu
Discovered
1963
Also known as
  • Calumetiet
  • Vondechenite

Where it forms, where it's found

Geological setting

Copper deposit in basalt. The chlorine is thought to have been due to connate water.

Corosion product of copper containing metals (ie Ramses ii stove in Cairo museum)

Type locality
Centennial Mine
  1. Centennial Heights
  2. Calumet Township
  3. Houghton County
  4. Michigan
  5. USA

47.2583°, -88.4286°

12recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Azure blue · Powder blue

In masses: Brilliant azure blue inclining to powder blue

Tenacity
brittle

Optical

Optical type
Biaxial · 2V measured = 2°
Refractive index
1.666 – 1.69
Surface relief
High
Principal indices
nα 1.666 · nβ 1.69 · nγ 1.69
Dispersion
r > v or r < v
Michel-Lévy diagramhighlighted lineδ = 0.0240
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]240 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation240 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Cmcm
Cell parameters
a = 6.653(1) Å · b = 15.034(3) Å · c = 6.611(1) Å
Ratio a:b:c
1 : 2.260 : 0.994
Z
2
Morphology

Basal pinacoid (001) and first order prism (110).

Type-locality form

Occurs as spherules and sheaves of scaly crystals.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper463.546254.184
44.34%
8OOxygenOxygen1215.999191.988
33.49%
17ClChlorineChlorine235.45070.900
12.37%
20CaCalciumCalcium140.07840.078
6.99%
1HHydrogenHydrogen161.00816.128
2.81%
Total573.278100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Calumetiet
  • Vondechenite

In other languages

French
calumetite
German
Calumetit
Italian
calumetite

Classification

Strunz
10th ed.

3.DA.40

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DAWith Cu, etc., without PbGroup
  • 3.DA.40CalumetiteSpecies
Dana
8th ed.

06.02.05.01

  • 06Hydroxides and Oxides Containing HydroxylClass
  • 06.02X(OH)2Type
  • 06.02.05— unnamed intermediate level —Group
  • 06.02.05.01CalumetiteSpecies
CIM

8.2.8

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.2Halides of CuGroup
  • 8.2.8CalumetiteSpecies

Literature, links & citation

Citations
  1. 1963Williams, Sidney A. (1963) Anthonyite and calumetite, two new minerals from the Michigan copper district. American Mineralogist, 48 (5-6) 614-619
  2. 2002Brandes, P.T., Robinson, G.W. (2002) A Preliminary Study of Calumetite and Other Copper Chloride Mineralization on the Keweenaw Peninsula, Michigan. Unpublished MSc thesis, Michigan Technological University, USA.
  3. 2005(2005) Calumetite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2019Miyawaki, Ritsuro, Hatert, Frédéric, Mills, Stuart J. (2019) New minerals and nomenclature modifications approved in 2019. CNMNC Newsletter 49. Mineralogical Magazine, 83 (3) 479-483 doi:10.1180/mgm.2019.35 DOI: 10.1180/mgm.2019.35
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Calumetite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/calumetite-870},
  note      = {Accessed 2026-05-11}
}