Caoxite

Ca(C2O4) · 3H2O
IMA status
  • Approved
IMA symbol
Cao
Also known as
  • Caoxiet
  • IMA1996-012

Where it forms, where it's found

Geological setting

veinlets cutting metamorphosed Mn–Ba-rich cherts in an obducted ophiolite.

Type locality
Cerchiara Mine
  1. Borghetto di Vara
  2. La Spezia Province
  3. Liguria
  4. Italy

44.1983°, 9.7075°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Colorless
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

(010)

Fracture
Irregular/Uneven
Density
1.87 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 70°
Refractive index
1.483 – 1.533
Surface relief
Moderate
Principal indices
nα 1.483 · nβ 1.516 · nγ 1.533
Dispersion
relatively strong
UV response
None observed
Michel-Lévy diagramhighlighted lineδ = 0.0500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]500 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation500 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 6.097(1) Å · b = 7.145(1) Å · c = 8.434(1) Å
Cell angles
α = 76.54(1) ° · β = 70.30(1) ° · γ = 70.75(1) °
Ratio a:b:c
1 : 1.172 : 1.383
Z
2
Type-locality form

spherulitic and isolated aggregates, up to 0.5 mm across, consisting of colorless, stocky crystals

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen715.999111.993
61.49%
20CaCalciumCalcium140.07840.078
22.00%
6CCarbonCarbon212.01124.022
13.19%
1HHydrogenHydrogen61.0086.048
3.32%
Total182.141100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Caoxiet
  • IMA1996-012

In other languages

French
Caoxite
German
Caoxit · IMA 1996-012
Italian
Caoxite
Japanese
カオックス石

Classification

Strunz
10th ed.

10.AB.50

  • 10Organic CompoundsClass
  • 10.ASalts of organic acidsDivision
  • 10.ABOxalatesGroup
  • 10.AB.50CaoxiteSpecies

Literature, links & citation

Citations
  1. 1997Basso, R., Lucchetti, G., Zefiro, L., Palenzona, A. (1997) Caoxite, Ca(H2O)3(C2O4), a new mineral from the Cerchiara mine, northern Apennines, Italy. Neues Jahrbuch für Mineralogie - Monatshefte, 1997 (2) 84-96 doi:10.1127/njmm/1997/1997/84DOI: 10.1127/njmm/1997/1997/84
  2. 1998Mandarino, Joseph A. (1998) Abstracts of New Mineral Descriptions. The Mineralogical Record, 29 (3) 233-237
  3. 1998Jambor, John L., Grew, Edward S., Roberts, Andrew C. (1998) New mineral names. American Mineralogist, 83 (1) 185-189
  4. 2005(2005) Caoxite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2005Echigo, T., Kimata, M., Kyono, A., Shimizu, M., Hatta, T. (2005) Re-investigation of the crystal structure of whewellite [Ca(C2O4)·H2O] and the dehydration mechanism of caoxite [Ca(C2O4)·3H2O]. Mineralogical Magazine, 69 (1) 77-88 doi:10.1180/0026461056910235DOI: 10.1180/0026461056910235
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Caoxite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/caoxite-6845},
  note      = {Accessed 2026-05-11}
}