Carboferriphoxite

[(NH4)K(H2CO3)][Fe3+(HPO4)(H2PO4)(C2O4)]
IMA status
  • Approved
IMA symbol
Cfphx
IMA approved
2024
Also known as
  • Carboferriphoxiet

Where it forms, where it's found

Geological setting

bat-guano-related, post-mining assemblage.

Type locality
125 foot level
  1. Rowley Mine
  2. Theba
  3. Painted Rock Mining District
  4. Painted Rock Mountains
  5. Maricopa County
  6. Arizona
  7. USA

33.0492°, -113.0330°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
colorless
Streak
white
Tenacity
brittle
Cleavage
Distinct/Good

two good cleavages (probably (100) and (001)).

Fracture
Splintery
Density
2.14 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 67°
Refractive index
1.525 – 1.63
Surface relief
Moderate
Principal indices
nα 1.525 · nβ 1.555 · nγ 1.630
Birefringence
s biaxial (+) with α = 1.525(3), β = 1.555(calc), γ = 1.630(3) and 2Vmeas. = 67(1)°
Pleochroism
Non-pleochroic
UV response
The mineral does not fluoresce in either long- or short-wave ultraviolet illumination.
Notes

β = 1.555(calc) good way to distinguish carboferriphoxite from ferriphoxite is by its distinctly higher birefringence, evidenced by higher order interference colours under crossed polars.

Michel-Lévy diagramhighlighted lineδ = 0.5250
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]5250 nmhigh order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation5250 nm
Orderhigh order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 6.4405(3) Å · b = 9.399(5) Å · c = 11.839(6) Å
Cell angles
α = 95.763(10) ° · β = 92.314(10) ° · γ = 100.665(8) °
Ratio a:b:c
1 : 1.459 : 1.838
Z
2
Twinning

No twinning was observed

Type-locality form

needles or blades, up to about 0.2 mm in length, typically forming fan- and bowtie-like sprays

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1515.999239.985
52.63%
15PPhosphorusPhosphorus230.97461.948
13.59%
26FeIronIron155.84555.845
12.25%
19KPotassiumPotassium139.09839.098
8.57%
6CCarbonCarbon312.01136.033
7.90%
7NNitrogenNitrogen114.00714.007
3.07%
1HHydrogenHydrogen91.0089.072
1.99%
Total455.988100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Carboferriphoxiet

In other languages

German
Carboferriphoxit

Classification

Strunz
10th ed.

10.AB.60

  • 10Organic CompoundsClass
  • 10.ASalts of organic acidsDivision
  • 10.ABOxalatesGroup
  • 10.AB.60CarboferriphoxiteSpecies

Literature, links & citation

Citations
  1. 2025Kampf, Anthony R.; Ma, Chi; Hawthorne, Frank C.; Marty, Joe (2025) Ferriphoxite and carboferriphoxite: two new oxalato-phosphate minerals from the Rowley mine, Arizona, USA. Mineralogical Magazine, 89 (1). 148-154 doi:10.1180/mgm.2024.56DOI: 10.1180/mgm.2024.56
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Carboferriphoxite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/carboferriphoxite-470989},
  note      = {Accessed 2026-05-11}
}