Carletonite

KNa4Ca4Si8O18(CO3)4(F,OH) · H2O
IMA status
  • Approved
IMA symbol
Cto
Discovered
1971
Also known as
  • Carletoniet
  • IMA1969-016

Where it forms, where it's found

Geological setting

In an alkaline complex in marble xenoliths in nepheline syenite.

Type locality
Poudrette quarry (De-Mix quarry
  1. Demix quarry
  2. Uni-Mix quarry
  3. Carrière Mont Saint-Hilaire
  4. MSH)
  5. Mont Saint-Hilaire
  6. La Vallée-du-Richelieu RCM
  7. Montérégie
  8. Québec
  9. Canada

45.5628°, -73.1417°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · Pearly
Transparency
Transparent · Translucent
Colour
Colourless · light blue · dark blue · or pink
Streak
White
Cleavage
Perfect

[001] Perfect, [110] Distinct

Fracture
Conchoidal
Density
2.45 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.517 – 1.521
Surface relief
Moderate
Principal indices
nω 1.521 · nε 1.517
Pleochroism
Weak

The blue variety shows a weak pleochroism, with O: very pale blue, E: very pale pinkish brown.

Michel-Lévy diagramhighlighted lineδ = 0.0040
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]40 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation40 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
P4/mbm
Cell parameters
a = 13.178 Å · c = 16.695 Å
Z
4
Type-locality form

Massive core, about 8 inches in diameter, of a xenolith

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3215.999511.968
46.62%
14SiSiliconSilicon828.085224.680
20.46%
20CaCalciumCalcium440.078160.312
14.60%
11NaSodiumSodium422.99091.960
8.37%
6CCarbonCarbon412.01148.044
4.38%
19KPotassiumPotassium139.09839.098
3.56%
9FFluorineFluorine118.99818.998
1.73%
1HHydrogenHydrogen31.0083.024
0.28%
Total1098.084100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Al
  • Mg

Synonyms

  • Carletoniet
  • IMA1969-016

In other languages

French
Carletonite
German
Carletonit · IMA 1969-016
Spanish
Carletonita
Italian
carletonite
Portuguese
carletonita · Carletonite
Japanese
カーレトン石
Chinese
碳矽鹼鈣石 · 碳硅碱钙石
Simplified Chinese
碳硅碱钙石
Traditional Chinese
碳矽碱钙石 · 碳矽鹼鈣石
Russian
Карлтонит

Classification

Strunz
10th ed.

9.EB.20

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EBDouble nets with 4- and 6-membered ringsGroup
  • 9.EB.20CarletoniteSpecies
Dana
8th ed.

72.03.01.04

  • 72Phyllosilicates Two-dimensional Infinite Sheets with Other Than Six-membered RingsClass
  • 72.03Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings with 3-, 4-, or 5-membered rings and 8-membered ringsType
  • 72.03.01Apophyllite group (4- & 8-membered rings)Group
  • 72.03.01.04CarletoniteSpecies
CIM

17.4.8

  • 17Silicates Containing other AnionsClass
  • 17.4Silicates with carbonatesGroup
  • 17.4.8CarletoniteSpecies

Literature, links & citation

Citations
  1. 1971Chao, George Y. (1971) Carletonite, KNa4Ca4Si8O18(CO3)4(F,OH)·H2O, a new mineral from, Mount St. Hilaire, Quebec. American Mineralogist, 56 (11-12) 1855-1866
  2. 1972Chao, George Y. (1972) The crystal structure of carletonite, KNa4Ca4Si8O18(CO3)4(F,OH)·H2O. American Mineralogist, 57 (5-6) 765-778
  3. 2010(2010) Carletonite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2013Frost, Ray L., Xi, Yunfei, Scholz, Ricardo, López, Andrés, Belotti, Fernanda Maria (2013) Infrared and Raman spectroscopic characterization of the silicate–carbonate mineral carletonite – KNa4Ca4Si8O18(CO3)4(OH,F)·H2O. Journal of Molecular Structure, 1042. 1-7 doi:10.1016/j.molstruc.2013.03.036DOI: 10.1016/j.molstruc.2013.03.036
  5. 2016Pohwat, Paul W., Cook, Robert B. (2016) Conniosseur's Choice: Carletonite, Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada. Rocks & Minerals, 91 (1) 48-53 doi:10.1080/00357529.2016.1099133DOI: 10.1080/00357529.2016.1099133
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Carletonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/carletonite-898},
  note      = {Accessed 2026-05-11}
}