Carlfrancisite

Mn2+3(Mn2+,Mg,Fe3+,Al)42(As3+O3)2(As5+O4)4[(Si,As5+)O4]6[(As5+,Si)O4]2(OH)42
IMA status
  • Approved
IMA symbol
Cfc
IMA approved
2012
Also known as
  • Carlfrancisiet
  • IMA2012-033
  • Unnamed (Mcgovernite-like mineral 2)

Where it forms, where it's found

Geological setting

Metamorphosed lenses associated with Cu-Pb-Ag sulfide ores in feldspathic sandstone that have subsequently been reworked by late hydrothermal solutions.

Type locality
E15-11 south stope
  1. 11 level
  2. Asis West sector
  3. Kombat Mine
  4. Kombat
  5. Otavi Constituency
  6. Otjozondjupa Region
  7. Namibia
2recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Pale yellow to yellow-orange
Streak
Very pale yellow
Tenacity
brittle
Cleavage
Perfect

Micaceous on (001)

Fracture
Hackly
Density
3.620 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.756 – 1.758
Surface relief
High
Principal indices
nω 1.756 · nε 1.758
Pleochroism
Non-pleochroic
UV response
Not fluorescent.
Notes

Refractive indices for 590 nm using a gel filter.

Michel-Lévy diagramhighlighted lineδ = 0.0020
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]20 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation20 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#85
Cell parameters
a = 8.2238(2) Å · c = 205.113(6) Å
Z
6
Twinning

None observed.

Parting
None observed
Type-locality form

Curved platy aggregates ~2 cm across.

Comment

Space group R-3c assumed by Hawthoren (2018); Lake and Von Dreele (2025) conclude it is R3c (non-centrosymmetric).

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese4554.9382472.210
25.17%
26FeIronIron4255.8452345.490
23.88%
8OOxygenOxygen9615.9991535.904
15.63%
13AlAluminiumAluminium4226.9821133.244
11.53%
33AsArsenicArsenic1474.9221048.908
10.68%
12MgMagnesiumMagnesium4224.3051020.810
10.39%
14SiSiliconSilicon828.085224.680
2.29%
1HHydrogenHydrogen421.00842.336
0.43%
Total9823.582100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Carlfrancisiet
  • IMA2012-033
  • Unnamed (Mcgovernite-like mineral 2)

In other languages

German
Carlfrancisit · IMA 2012-033
Italian
carlfrancisite

Classification

Strunz
10th ed.

8.BE.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BEWith only medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.BE.45CarlfrancisiteSpecies
Dana
8th ed.

43.04.09.03

  • 43Compound Phosphates, Etc.Class
  • 43.04Anhydrous Compound Phosphates, etc·, Containing Hydroxyl or HalogenType
  • 43.04.09Mcgovernite GroupGroup
  • 43.04.09.03CarlfrancisiteSpecies

Literature, links & citation

Citations
  1. 2012Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2012) New minerals and nomenclature modifications approved in 2012. CNMNC Newsletter No 14. Mineralogical Magazine, 76 (5) 1281-1288 doi:10.1180/minmag.2012.076.5.15DOI: 10.1180/minmag.2012.076.5.15
  2. 2013Hawthorne, Frank C., Abdu, Yassir A., Ball, Neil A., Pinch, William W. (2013) Carlfrancisite: Mn2+3(Mn2+,Mg,Fe3+,Al)42(As3+O3)2(As5+O4)4[(Si,As5+)O4]6[(As5+,Si)O4]2(OH)42, a new arseno-silicate mineral from the Kombat mine, Otavi Valley, Namibia. American Mineralogist, 98 (10) 1693-1696 doi:10.2138/am.2013.4426 DOI: 10.2138/am.2013.4426
  3. 2017(2017) Carlfrancisite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2018Hawthorne, Frank C. (2018) Long-range and short-range cation order in the crystal structures of carlfrancisite and mcgovernite. Mineralogical Magazine, 82 (5) 1101-1118 doi:10.1180/minmag.2017.081.098DOI: 10.1180/minmag.2017.081.098
  5. 2025Lake, Charles; Von Dreele, Robert (2025) The structures of mcgovernite and carlfrancisite reconsidered: static disorder or ordered defects and twinning? Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, 81 (6). 572-581 doi:10.1107/s2052520625009175DOI: 10.1107/s2052520625009175
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Carlfrancisite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/carlfrancisite-43359},
  note      = {Accessed 2026-05-11}
}