Carlhintzeite

Ca2AlF7 · H2O
IMA status
  • Approved
IMA symbol
Chz
Discovered
1979
Also known as
  • Carlhintzeiet
  • IMA1978-031

Where it forms, where it's found

Geological setting

Late-stage phosphate mineralization in granite pegmatite

Type locality
Hagendorf South Pegmatite
  1. Hagendorf
  2. Waidhaus
  3. Neustadt an der Waldnaab District
  4. Upper Palatinate
  5. Bavaria
  6. Germany

49.6503°, 12.4597°

10recorded occurrences
Source · OpenStreetMap

Physical

Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Colorless
Streak
White
Tenacity
brittle
Cleavage
None Observed
Density
2.86 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 77° · 2V calc = 78 – 86°
Refractive index
1.411 – 1.422
Surface relief
Low
Principal indices
nα 1.411 · nβ 1.416 · nγ 1.422
Birefringence
0.011
Pleochroism
Non-pleochroic
Dispersion
r > v
Extinction
X ~ b, Z^c = 10°
Michel-Lévy diagramhighlighted lineδ = 0.0110
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]110 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation110 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Cell parameters
a = 9.485 Å · b = 6.983 Å · c = 9.305 Å
Cell angles
α = 91.14 ° · β = 104.85 ° · γ = 90.0 °
Ratio a:b:c
1 : 0.736 : 0.981
Z
4
Morphology

Bladed crystals with (100), (001), and (110). Elongated parallel to (110) and flattened on (001).

Twinning

Always twinned by rotation on (101)

Type-locality form

Small white bladed crystals in open radial clusters

Comment

Point Group: 1or _1; Space Group: C1 or C_1.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
9FFluorineFluorine718.998132.986
51.52%
20CaCalciumCalcium240.07880.156
31.05%
13AlAluminiumAluminium126.98226.982
10.45%
8OOxygenOxygen115.99915.999
6.20%
1HHydrogenHydrogen21.0082.016
0.78%
Total258.139100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Carlhintzeiet
  • IMA1978-031

In other languages

German
Carlhintzeit · IMA 1978-031
Italian
Carlhintzeite

Classification

Strunz
10th ed.

3.CB.45

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CBNeso-aluminofluoridesGroup
  • 3.CB.45CarlhintzeiteSpecies
Dana
8th ed.

11.06.07.01

  • 11Halide ComplexesClass
  • 11.06Aluminofluorides - Isolated OctahedraType
  • 11.06.07— unnamed intermediate level —Group
  • 11.06.07.01CarlhintzeiteSpecies
CIM

8.6.15

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.6Halides of AlGroup
  • 8.6.15CarlhintzeiteSpecies

Literature, links & citation

Citations
  1. 1979Dunn, Pete J., Peacor, Donald R., Sturman, B. Darko (1979) Carlhintzeite, a new calcium aluminum fluoride hydrate from the Hagendorf pegmatites, Bavaria, Germany. The Canadian Mineralogist, 17 (1) 103-105
  2. 1980Fleischer, M.; Mandarino, J.A.; Pabst, A. (1980) New mineral names. American Mineralogist, 65 (1-2). 205-210
  3. 2007(2007) Carlhintzeite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2010Kampf, A. R., Colombo, F., González del Tánago, J. (2010) Carlhintzeite, Ca2AlF7·H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: description and crystal structure. Mineralogical Magazine, 74 (4) 623-632 doi:10.1180/minmag.2010.074.4.623 DOI: 10.1180/minmag.2010.074.4.623
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Carlhintzeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/carlhintzeite-900},
  note      = {Accessed 2026-05-11}
}