Carlsonite

(NH4)5Fe3+3O(SO4)6 · 7H2O
IMA status
  • Approved
IMA symbol
Csn
IMA approved
2014
Also known as
  • Carlsoniet
  • IMA2014-067

Where it forms, where it's found

Geological setting

Carlsonite was produced by the condensation of gases in the oil-shale fire. The shale fire occurred in a rock outcrop of the Late Devonian Huron Shale Member of the Ohio Shale along River Road, northeast of the town of Monroeville in Ridgefield Township, Huron County. At the time of inspection, geologists were uncertain of the cause. The current hypothesis suggests the fire started in September 2009 as the result of spontaneous combustion. The shale fire burned until March 2011 and created a variety of exotic mineral species, such as boussinggaulite and lonecreekite, as well as the never-before-observed carlsonite.

Type locality
Huron Shale burn site
  1. Huron River
  2. Huron County
  3. Ohio
  4. USA

41.2781°, -82.6742°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
yellow to orange-brown
Streak
tan
Tenacity
brittle
Cleavage
Perfect

(001)

Fracture
Irregular/Uneven
Density
2.167 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 80° · 2V calc = 78°
Refractive index
1.576 – 1.591
Surface relief
Moderate
Principal indices
nα 1.576 · nβ 1.585 · nγ 1.591
Pleochroism

yellow (X), orange (Y & Z); X < Y ~ Z

Dispersion
strong (r > v)
UV response
not observed
Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 9.5927(2) Å · b = 9.7679(3) Å · c = 18.3995(13) Å
Cell angles
α = 93.250(7) ° · β = 95.258(7) ° · γ = 117.993(8) °
Ratio a:b:c
1 : 1.018 : 1.918
Unit cell volume
1506.15 ų
Z
2
Morphology

Forms observed: (100), (001), (110), (111), (111), (012)

Twinning

cross-hatched, rare

Type-locality form

It occurs in crystal form as thin to thick tablets up to about 0.5 mm but often much smaller; the tablets are flattened on {001); at this scale, the yellow to orange-brown crystals are best viewed through a high-powered microscope; also as stout prisms el

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3215.999511.968
52.45%
16SSulfurSulfur632.060192.360
19.71%
26FeIronIron355.845167.535
17.16%
7NNitrogenNitrogen514.00770.035
7.17%
1HHydrogenHydrogen341.00834.272
3.51%
Total976.170100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Carlsoniet
  • IMA2014-067

In other languages

German
Carlsonit · IMA 2014-067
Italian
carlsonite

Classification

Strunz
10th ed.

7.DF

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DFCarlsoniteSpecies

Literature, links & citation

Citations
  1. 2010Larsen, G. (2010) Survey inspects a rare Ohio geohazard. Ohio Geology: 1: 7.
  2. 2010Carlson, E. (2010) Analysis of Huron River shale fire minerals reveals two specimens new to Ohio. Ohio Geology: 2: 7.
  3. 2014Kampf, A. R., Richards, R. P., Nash, B. P. (2014) The 2H and 3R polytypes of sabieite, NH4Fe3+(SO4)2, from a natural fire in an oil-bearing shale near Milan, Ohio. American Mineralogist, 99 (7) 1500-1506 doi:10.2138/am.2014.4884DOI: 10.2138/am.2014.4884
  4. 2015Blake, D. (2015) Carlsonite: New mineral species discovered in northern Ohio. Ohio Department of Natural Resources, Ohio Geology Extra, http://geosurvey.ohiodnr.gov/extra-news-archives/2015-articles/carlsonite.
  5. 2015Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2014 and 2015. Newsletter No 23. Mineralogical Magazine, 79 (1) 51-58 doi:10.1180/minmag.2015.079.1.05DOI: 10.1180/minmag.2015.079.1.05
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Carlsonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/carlsonite-46504},
  note      = {Accessed 2026-05-11}
}