Cetineite

NaK5Sb14S6O18(H2O)6
IMA status
  • Approved
IMA symbol
Cet
Discovered
1986
IMA approved
1986
Also known as
  • Cetineiet
  • IMA1986-019

Where it forms, where it's found

Geological setting

Antimony deposit, on roasted ore that has been weathered.

Type locality
Le Cetine di Cotorniano mine
  1. Chiusdino
  2. Siena Province
  3. Tuscany
  4. Italy

43.2320°, 11.1683°

6recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Orange-red
Streak
Orange
Tenacity
sectile
Cleavage
Distinct/Good

on (1000)

Density
4.21 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.74
Surface relief
High
Principal indices
nω 1.74
Pleochroism
Weak

From orange to slightly orange-brown.

UV response
Not fluorescent.

Crystallography

Crystal system
Hexagonal
Space group
#104
Cell parameters
a = 14.2513(3) Å · c = 5.5900(1) Å
Z
2
Morphology

Tufts of acicular crystals.

Type-locality form

Tufts of orange-red acicular crystals, elongate [001] and up to 15 mm in length and 15 µm diameter.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
51SbAntimonyAntimony14121.7601704.640
67.87%
8OOxygenOxygen2415.999383.976
15.29%
19KPotassiumPotassium539.098195.490
7.78%
16SSulfurSulfur632.060192.360
7.66%
11NaSodiumSodium122.99022.990
0.92%
1HHydrogenHydrogen121.00812.096
0.48%
Total2511.552100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • S
  • Si

Synonyms

  • Cetineiet
  • IMA1986-019

In other languages

German
Cetineit · IMA 1986-019
Italian
Cetineite

Classification

Strunz
10th ed.

2.MA.05

  • 2Sulfides and SulfosaltsClass
  • 2.MOxysulfosaltsDivision
  • 2.MAOxysulfosalts of Alkalies and Alkali EarthsGroup
  • 2.MA.05CetineiteSpecies
Dana
8th ed.

02.13.03.01

  • 02SulfidesClass
  • 02.13OxysulfidesType
  • 02.13.03— unnamed intermediate level —Group
  • 02.13.03.01CetineiteSpecies
CIM

24.1.2

  • 24Antimonates and AntimonitesClass
  • 24.1Antimonates and antimonites of Na, Cu or AgGroup
  • 24.1.2CetineiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1987Sabelli, C., Vezzalini, G. (1987) Cetineite, a new antimony oxide-sulfide mineral from Cetine mine, Tuscany, Italy. Neues Jahrbuch für Mineralogie - Monatshefte, 1987. 419-425
  2. 1988Sabelli, Cesare, Nakai, Izumi, Katsura, Shigeo (1988) Crustal structures of cetineite and its synthetic Na analogue Na3.6(Sb2O3)3(SbS3)(OH)0.6·2.4H2O. American Mineralogist, 73 (3-4) 398-404
  3. 1989Jambor, John L., Burke, Ernst A. J. (1989) New Mineral Names. American Mineralogist, 74 (11-12) 1399-1404
  4. 2005(2005) Cetineite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cetineite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cetineite-943},
  note      = {Accessed 2026-05-11}
}