Chalcocyanite

Cu(SO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ccy
Discovered
1868
Also known as
  • Chalcocyaniet
  • Chalcocyanit
  • Chalcocyanita
  • +8 more

Where it forms, where it's found

Geological setting

Active volcanic fumaroles.

Sublimates near volcanic fumaroles.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
18recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless · light green · brownish · yellowish · sky-blue · colourless in transitted light
Density
3.65 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 70° · 2V calc = 78°
Refractive index
1.724 – 1.739
Surface relief
High
Principal indices
nα 1.724 · nβ 1.733 · nγ 1.739
Dispersion
r > v medium
Notes

2V (measured) is large

Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 6.709(1) Å · b = 8.409(1) Å · c = 4.833(1) Å
Ratio a:b:c
1 : 1.253 : 0.720
Z
4
Morphology

Crystals frequently tabular (010) and slightly elongated [001].

Type-locality form

Sublimates

Comment

Space Group: P nmb

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
40.10%
29CuCopperCopper163.54663.546
39.81%
16SSulfurSulfur132.06032.060
20.09%
Total159.602100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Chalcocyaniet
  • Chalcocyanit
  • Chalcocyanita
  • Hydrocyan
  • Hydrocyanit
  • Hydrocyanita
  • Hydrocyanite
  • Hydrokyanit
  • Hydrokyanita
  • Hydrokyanite
  • Idrociano

In other languages

German
Chalkocyanit · Hydrocyan · Hydrocyanit · Hydrokyanit
Italian
Calcocianite · Idrociano
Portuguese
calcocianita · Calcocianite

Classification

Strunz
10th ed.

7.AB.10

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ABWith medium-sized cationsGroup
  • 7.AB.10ChalcocyaniteSpecies
Dana
8th ed.

28.03.03.01

  • 28Anhydrous Acid and Normal SulfatesClass
  • 28.03AXO4Type
  • 28.03.03— unnamed intermediate level —Group
  • 28.03.03.01ChalcocyaniteSpecies
CIM

25.2.1

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.1ChalcocyaniteSpecies

Literature, links & citation

Citations
  1. 1873Scacchi (1873) Reale accademia delle scienze fisische e matematiche, Att., Naples: 5: 26 (as Idrociano).
  2. 1892Dana, Edward Salisbury; Dana, James Dwight (1892) A System of Mineralogy (6th ed.). John Wiley & Sons, Inc.
  3. 1929Posnjak, E., Tunell, G. (1929) The system cupric oxide-sulphur trioxide-water. American Journal of Science: 18: 1-34 (27).
  4. 1935Zambonini, Ferruccio (1935) Mineralogia Vesuviana, second edition with Quercigh, 463 pp., Naples: 158.
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chalcocyanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chalcocyanite-963},
  note      = {Accessed 2026-05-11}
}