Chalconatronite

Na2Cu(CO3)2 · 3H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Chna
Discovered
1955
Also known as
  • Chalconatroniet
  • Chalconatronit
  • Chalconatronita

Where it forms, where it's found

Geological setting

Originally found as alteration of bronze artifacts.

Secondary mineral in oxidation zones

Type locality
Egypt
23recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Greenish-blue to pale blue
Density
2.27 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70° · 2V calc = 86°
Refractive index
1.483 – 1.576
Surface relief
Moderate
Principal indices
nα 1.483 · nβ 1.53 · nγ 1.576
Pleochroism
Strong

X= nearly colorless Y= pale blue Z= blue

Dispersion
none
Extinction
Z ⊥ flattening; Y ‖ elongation; Z ∧ c = very small.
Michel-Lévy diagramhighlighted lineδ = 0.0930
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]930 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation930 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 9.7 Å · b = 6.09 Å · c = 13.82 Å
Cell angles
β = 91.92 °
Ratio a:b:c
1 : 0.628 : 1.425
Morphology

Fine grained crusts of pseudohexagonal plates or laths, massive, blebs, films.

Type-locality form

Fine-grained, greenish-blue crust,

Comment

Synthetic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen915.999143.991
50.78%
29CuCopperCopper163.54663.546
22.41%
11NaSodiumSodium222.99045.980
16.21%
6CCarbonCarbon212.01124.022
8.47%
1HHydrogenHydrogen61.0086.048
2.13%
Total283.587100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Chalconatroniet
  • Chalconatronit
  • Chalconatronita

In other languages

German
Chalkonatronit
Italian
calconatronite

Classification

Strunz
10th ed.

5.CB.40

  • 5CarbonatesClass
  • 5.CCarbonates without additional anions, with H2ODivision
  • 5.CBWith large cations (alkali and alkali-earth carbonates)Group
  • 5.CB.40ChalconatroniteSpecies
Dana
8th ed.

15.02.03.01

  • 15Hydrated Normal CarbonatesClass
  • 15.02AmBn(XO3)p·xH2O, with (m+n):p > 1:1Type
  • 15.02.03— unnamed intermediate level —Group
  • 15.02.03.01ChalconatroniteSpecies
CIM

11.2.4

  • 11CarbonatesClass
  • 11.2Carbonates of CuGroup
  • 11.2.4ChalconatroniteSpecies

Literature, links & citation

Citations
  1. 1955Fleischer, M. (1955) New mineral names. American Mineralogist, 40 (9-10). 941-944
  2. 1955Frondel, C., Gettens, R.J. (1955) Chalconatronite, a new mineral from Egypt. Science: 122: 75-76.
  3. 1955Gettens, R.J., Frondel, C. (1955) Chalconatronite: an alteration product on some ancient Egyptian bronzes. Studies in Conservation: 2(2): 64-75.
  4. 1973Brotherton, P.D., White, A.H. (1973) Crystal Structures of copper (II) sodium carbonate trihydrate (chalconatronite). Journal of the Chemical Society: 21: 2338-2340.
  5. 1978Mosset, A., Bonnet, J.J., Galy, J. (1978) Structure cristalline de la chalconatronite synthétique: Na2Cu(CO3)2·3H2O. Zeitschrift für Kristallographie: 148: 165-177.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chalconatronite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chalconatronite-954},
  note      = {Accessed 2026-05-11}
}