Cherokeeite

[Pb2Zn(OH)4](SO4) · H2O
IMA status
  • Approved
IMA symbol
Chrk
Also known as
  • Cherokeeiet

Where it forms, where it's found

Geological setting

"highly unusual secondary assemblage that comprises a variety of rare Pb-Zn-Cu sulfates, thiosulfates, and carbonates"

Type locality
Redmond Mine
  1. Waterville Lake
  2. Haywood County
  3. North Carolina
  4. USA

35.6802°, -83.0186°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
colourless to pale pink
Streak
white
Tenacity
brittle
Cleavage
Perfect

at least 2 directions

Fracture
Splintery
Density
5.011 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 85°
Refractive index
1.745 – 1.805
Surface relief
High
Principal indices
nα 1.745 · nβ 1.770 · nγ 1.805
Michel-Lévy diagramhighlighted lineδ = 0.0600
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]600 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation600 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 17.1697(2) Å · b = 6.4717(2) Å · c = 17.5304(12) Å
Cell angles
β = 115.440(8) °
Ratio a:b:c
1 : 0.377 : 1.021
Type-locality form

prisms or blades, to ca. 1 mm

Comment

space group is P21/n

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead2207.200414.400
62.61%
8OOxygenOxygen915.999143.991
21.76%
30ZnZincZinc165.38065.380
9.88%
16SSulfurSulfur132.06032.060
4.84%
1HHydrogenHydrogen61.0086.048
0.91%
Total661.879100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Cherokeeiet

In other languages

German
Cherokeeit · IMA 2022-016

Classification

Strunz
10th ed.

7.DF

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DFCherokeeiteSpecies

Literature, links & citation

Citations
  1. 2022Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 68. European Journal of Mineralogy, 34 (5) 385-391 doi:10.5194/ejm-34-385-2022 DOI: 10.5194/ejm-34-385-2022
  2. 2023Kampf, Anthony R.; Smith, Jason B.; Hughes, John M.; Ma, Chi; Emproto, Christopher (2023) New Minerals from the Redmond Mine, North Carolina, USA: III. Cherokeeite and Cuprocherokeeite, Two New Minerals Containing [Pb2(Zn,Cu2+)(OH)4]2+ Chains. The Canadian Journal of Mineralogy and Petrology, 61 (3). 635-647 doi:10.3749/2300001DOI: 10.3749/2300001
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cherokeeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cherokeeite-56154},
  note      = {Accessed 2026-05-11}
}